A detailed study on the structure, growth, and morphology of epitaxial Pb layers on Si(111) is presented. Grey et al. already determined the structures of the Si(111)(7×7)-Pb and Si(111)(√3 × √3 )R30°-Pb(β) monolayer phases with grazing-incidence x-ray diffraction. Our experimental data mainly support their models. In addition, we show that the Pb sites of the incommensurate √3 × √3 phase are spatially modulated by the substrate corrugation potential. At higher coverages, the Pb atoms form three-dimensional islands that are either oriented parallel to the Si lattice or slightly twisted. The twist angles are different for the 7×7 and √3 × √3 interfaces and can be understood on the basis of simple geometrical arguments. Also, the morphologies of the thick overlayers are different for the two types of interfaces. We argue that both phenomena can be understood if one assumes that the 7×7 and √3 × √3 interface structures remain preserved after depositing thick overlayers.

• Received 3 October 1991

DOI:https://doi.org/10.1103/PhysRevB.45.5991