Exchange and correlation in density-functional theory

L. J. Sham
Phys. Rev. B 32, 3876 – Published 15 September 1985
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Abstract

Expressions for the exchange-correlation energy and potential are given in terms of the perturbation series of the Coulomb interaction. The asymptotic behavior of the exchange-correlation potential for a confined system is derived. Improvement over the local-density approximation is explored.

  • Received 15 April 1985

DOI:https://doi.org/10.1103/PhysRevB.32.3876

©1985 American Physical Society

Authors & Affiliations

L. J. Sham

  • Department of Physics, University of CaliforniaSan Diego, La Jolla, California 92093

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Issue

Vol. 32, Iss. 6 — 15 September 1985

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