Effective-liquid approach to the generalized Onsager theories of the isotropic-nematic transition of hard convex bodies

José A. Cuesta, Carlos F. Tejero, Hong Xu, and Marc Baus
Phys. Rev. A 44, 5306 – Published 1 October 1991
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Abstract

Recent attempts to generalize the classical Onsager theory of nematic ordering to finite-density systems of finite-length hard convex bodies are related and compared. It is pointed out that, although good results can be obtained in three dimensions (3D), in two dimensions (2D) the underlying factorization approximation of the radial and angular variables always implies a second-order isotropic-nematic transition instead of the crossover from a weakly first-order transition to a continuous (Kosterlitz-Thouless) transition as seen in the simulations. The quantitative agreement with the simulations is also much poorer in 2D than in 3D. On the contrary, for large spatial dimensions these theories become exact.

  • Received 3 May 1991

DOI:https://doi.org/10.1103/PhysRevA.44.5306

©1991 American Physical Society

Authors & Affiliations

José A. Cuesta and Carlos F. Tejero

  • Facultad de Ciencias Físicas, Universidad Complutense de Madrid, 28040 Madrid, Spain

Hong Xu

  • Van’t Hoff Laboratorium, Rijkuniversiteit te Utrecht, NL-3508TB Utrecht, The Netherlands

Marc Baus

  • Physique Statistique et Plasmas, Code Postal 231, Université Libre de Bruxelles, B-1050 Brussels, Belgium

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Issue

Vol. 44, Iss. 8 — October 1991

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