Abstract
A multichannel quantum-defect theory focused on the time-delay matrix is applied to the analysis of Rydberg levels and autoionization resonances of the chlorine atom. The analysis shows that recently observed photoionization cross sections above the 3P) threshold of the chlorine ion may be interpreted in terms of unresolved groups of resonances with three different total angular momenta J and approximately the same energy. Experimental data of Rydberg levels were used to determine the phase shift of the collisional eigenstate (quantum defect) and the time-delay matrix for the electron-ion scattering process. The LS coupling scheme is assumed for the electron + ion compound state. The channel interaction strengths and dipole matrix elements of even-parity states relevant to electron-ion collisional and recombination processes are obtained. The branching ratio of photoelectrons is calculated.
- Received 5 March 1984
DOI:https://doi.org/10.1103/PhysRevA.31.1515
©1985 American Physical Society