Phase Diagram of Star Polymer Solutions

M. Watzlawek, C. N. Likos, and H. Löwen
Phys. Rev. Lett. 82, 5289 – Published 28 June 1999
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Abstract

The phase diagram of star polymer solutions in a good solvent is obtained over a wide range of densities and arm numbers by Monte Carlo simulations. The effective interaction between the stars is modeled by an ultrasoft pair potential which is logarithmic in the core-core distance. Among the stable phases are a fluid as well as body-centered cubic, face-centered cubic, body-centered orthogonal, and diamond crystals. In a limited range of arm numbers, reentrant melting and reentrant freezing transitions occur for increasing density.

  • Received 13 January 1999

DOI:https://doi.org/10.1103/PhysRevLett.82.5289

©1999 American Physical Society

Authors & Affiliations

M. Watzlawek1,*, C. N. Likos1,2, and H. Löwen1,2

  • 1Institut für Theoretische Physik II, Heinrich-Heine-Universität, Universitätsstraße 1, D-40225 Düsseldorf, Germany
  • 2IFF Theorie II, Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany

  • *Corresponding author.Email address: martin@thphy.uni-duesseldorf.de

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Vol. 82, Iss. 26 — 28 June 1999

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