Concentration Fluctuations in a Polymer Solution under a Temperature Gradient

W. B. Li, K. J. Zhang, J. V. Sengers, R. W. Gammon, and J. M. Ortiz de Zárate
Phys. Rev. Lett. 81, 5580 – Published 21 December 1998
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Abstract

We have performed small-angle Rayleigh light-scattering measurements in polymer solutions under various externally applied temperature gradients. Our experiments confirm the existence of an enhancement of the concentration fluctuations. The nonequilibrium concentration fluctuations are proportional to (T)2/k4, where T is the applied temperature gradient, and k is the wave number of the fluctuations. The measured strengths of the nonequilibrium fluctuations in the dilute and semidilute concentration regime agree with the strengths calculated from fluctuating hydrodynamics.

  • Received 15 June 1998

DOI:https://doi.org/10.1103/PhysRevLett.81.5580

©1998 American Physical Society

Authors & Affiliations

W. B. Li1, K. J. Zhang1, J. V. Sengers1,2, R. W. Gammon1, and J. M. Ortiz de Zárate3

  • 1Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742
  • 2Department of Chemical Engineering, University of Maryland, College Park, Maryland 20742
  • 3Facultad de Ciencias Físicas, Universidad Complutense, 28040 Madrid, Spain

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Vol. 81, Iss. 25 — 21 December 1998

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