Abstract
Crystalline , after exposure to air, is shown to exhibit the characteristic luminescence spectrum of singlet molecular oxygen. The role of oxygen is verified by measuring the large isotope shift of the vibrational mode luminescence replica in a sample prepared with . Detailed spectroscopy reveals novel bands in the spectrum which arise from vibronic coupling of the transition to the molecules. This allows measurement of the vibrational spectrum with unparalleled sensitivity and precision from mg-sized samples.
- Received 12 June 1992
DOI:https://doi.org/10.1103/PhysRevLett.69.2423
©1992 American Physical Society