Molecular Dynamics Study of Infinitely Thin Hard Rods: Scaling Behavior of Transport Properties

Daan Frenkel and John F. Maguire
Phys. Rev. Lett. 47, 1025 – Published 12 October 1981
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Abstract

A molecular dynamics study on a system of infinitely thin hard rods is reported. At low densities, rotational and translational diffusion is adequately described by the Enskog theory, but at high densities (ρ*1) large deviations are observed. For ρ*1, the rotational diffusion constant (Dr) and the longitudinal translational diffusion constant (D) are compared with scaling predictions. The molecular dynamics results confirm that Drρ*2, and are consistent with a predicted divergence of Dρ*12.

  • Received 29 June 1981

DOI:https://doi.org/10.1103/PhysRevLett.47.1025

©1981 American Physical Society

Authors & Affiliations

Daan Frenkel*

  • Koninklijke /Shell Laboratorium, 1031-CM Amsterdam, The Netherlands

John F. Maguire

  • Laboratorium voor Fysische Chemie, Universiteit van Amsterdam, 1018-WS Amsterdam, The Netherlands

  • *Present address: Fysisch Laboratorium, Rijks Universiteit, Princetonplein 5, 3584-CC Utrecht, The Netherlands.
  • Present address: School of Physical Sciences, The New University of Ulster, Coleraine BT52 1SA, Northern Ireland.

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Vol. 47, Iss. 15 — 12 October 1981

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