X-Ray—Scattering Evidence for Sublattice Phase Transition in Stoichiometric Silver β-Alumina

J. P. Boilot, Ph. Colomban, R. Collongues, G. Collin, and R. Comès
Phys. Rev. Lett. 42, 785 – Published 19 March 1979
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Abstract

X-ray-scattering investigation of stoichiometric silver β-alumina reveals a clear phase transition between the high-temperature conducting-ions quasiliquid sublattice, and a lowtemperature crystalline state. Preliminary, structural analysis of the low-temperature crystalline order confirms the type of organization previously deduced for the low-temperature short-range order of nonstoichiometric silver β-alumina.

  • Received 28 December 1978

DOI:https://doi.org/10.1103/PhysRevLett.42.785

©1979 American Physical Society

Authors & Affiliations

J. P. Boilot, Ph. Colomban, and R. Collongues

  • Laboratoire de Chimie Appliquée de l'Etat Solide, 75005 Paris, France

G. Collin* and R. Comès

  • Laboratoire de Physique des Solides associé au Centre Nationale de la Recherche Scientifique, Université Paris-Sud, 91405 Orsay, France

  • *Permanent address: Laboratoire associé au Centre National de la Recherche Scientifique, No. 200 4, Avenue de l'Observatoire, 75006 Paris, France.

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Vol. 42, Iss. 12 — 19 March 1979

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