Abstract
We have determined the interconfiguration mixing ratios (/) of 1.4 and 4.1 for S and Sm at 295 K from their x-ray photoemission spectra. These ratios are observed to decrease reversibly by a factor of 2 at 110 K. The agreement of these results with valences deduced from lattice-constant measurements is direct evidence that configuration mixing is responsible for the anomalous temperature- and composition-dependence of the lattice constant.
- Received 17 June 1974
DOI:https://doi.org/10.1103/PhysRevLett.33.820
©1974 American Physical Society