Short-range smectic fluctuations and the flexoelectric model of modulated nematic liquid crystals

Nataša Vaupotič, Samo Curk, Mikhail A. Osipov, Mojca Čepič, Hideo Takezoe, and Ewa Gorecka
Phys. Rev. E 93, 022704 – Published 12 February 2016

Abstract

We show that the flexoelectric model of chiral and achiral modulated nematics predicts the compression modulus that is by orders of magnitude lower than the measured values. The discrepancy is much larger in the chiral modulated nematic phase, in which the measured value of the compression modulus is of the same order of magnitude as in achiral modulated nematics, even though the heliconical pitch is by an order of magnitude larger. The relaxation of a one-constant approximation in the biaxial elastic model used for chiral modulated nematics does not solve the problem. Therefore, we propose a structural model of the modulated nematic phase, which is consistent with the current experimental evidence and can also explain large compression modulus: the structure consists of short-range smectic clusters with a fourfold symmetry and periodicity of two molecular distances. In chiral systems, chiral interactions lead to a helicoidal structure of such clusters.

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  • Received 30 October 2015
  • Revised 22 December 2015

DOI:https://doi.org/10.1103/PhysRevE.93.022704

©2016 American Physical Society

Physics Subject Headings (PhySH)

  1. Physical Systems
  1. Techniques
Polymers & Soft Matter

Authors & Affiliations

Nataša Vaupotič1,2, Samo Curk1, Mikhail A. Osipov3, Mojca Čepič2,4, Hideo Takezoe5,6, and Ewa Gorecka6

  • 1Faculty of Natural Sciences and Mathematics, University of Maribor, Koroška 160, 2000 Maribor, Slovenia
  • 2Jozef Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia
  • 3Department of Mathematics and Statistics, University of Strathclyde, 26 Richmond Street, G1 Glasgow, United Kingdom
  • 4Faculty of Education, University of Ljubljana, Kardeljeva ploščad 16, 1000 Ljubljana, Slovenia
  • 5Toyota Physical and Chemical Research Institute, 41-1 Yokomichi, Nagakute, Aichi 480-1192, Japan
  • 6Department of Chemistry, University of Warsaw, Zwirki i Wigury 101, 02-089 Warsaw, Poland

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Issue

Vol. 93, Iss. 2 — February 2016

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