Macroscopic order in a nematic liquid crystal: Perturbation by spontaneous director fluctuations

Daichi Hamasuna, Rauzah Hashim, Atsuhiro Kasatani, Geoffrey R. Luckhurst, Akihiko Sugimura, Bakir A. Timimi, and Herbert Zimmermann
Phys. Rev. E 91, 062502 – Published 4 June 2015

Abstract

The dynamic alignment of the nematic director by near-orthogonal electric and magnetic fields has been investigated. The intermediate states during the relaxation process were found, with the aid of time-resolved deuterium NMR spectroscopy, to be markedly nonuniform. The macroscopic order was perturbed, although the initial and final states of the director appear to be essentially uniform. However, the initial state does have a profound influence on the uniformity of the director in the intermediate states. We have developed a fundamental model based on the effect of spontaneous director fluctuations to explain these unusual NMR observations.

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  • Received 18 February 2014

DOI:https://doi.org/10.1103/PhysRevE.91.062502

©2015 American Physical Society

Authors & Affiliations

Daichi Hamasuna1, Rauzah Hashim2, Atsuhiro Kasatani1, Geoffrey R. Luckhurst3, Akihiko Sugimura1,*, Bakir A. Timimi3, and Herbert Zimmermann4

  • 1School of Information Systems Engineering, Osaka Sangyo University, 3-1-1 Nakagaito, Daito-Shi, Osaka 574-4853, Japan
  • 2School of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
  • 3Department of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, United Kingdom
  • 4Department of Biophysics, Max-Planck-Institut für Medizinische Forschung, Jahnstrasse 29, D-69120 Heidelberg, Germany

  • *sugimura@ise.osaka-sandai.ac.jp

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Vol. 91, Iss. 6 — June 2015

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