The phase behavior of helical packings of thermoresponsive microspheres inside glass capillaries is studied as a function of the volume fraction. Stable packings with long-range orientational order appear to evolve abruptly to disordered states as the particle volume fraction is reduced, consistent with recent hard-sphere simulations. We quantify this transition using correlations and susceptibilities of the orientational order parameter ${\psi }_6$. The emergence of coexisting metastable packings, as well as coexisting ordered and disordered states, is also observed. These findings support the notion of phase-transition-like behavior in quasi-one-dimensional systems.

• Received 17 December 2009

DOI:https://doi.org/10.1103/PhysRevE.81.040401