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Nematic and almost-tetratic phases of colloidal rectangles

Kun Zhao, Christopher Harrison, David Huse, W. B. Russel, and P. M. Chaikin
Phys. Rev. E 76, 040401(R) – Published 11 October 2007

Abstract

Nonspherical colloids can exhibit liquid-crystalline phases with different degrees of broken orientational and translational symmetry. Here we investigate hard rectangles consisting of photolithographically prepared disks standing on edge. We observe a conventional Kosterlitz-Thouless transition from isotropic to nematic with almost smectic behavior at high density. But just on the isotropic side of the isotropic to nematic transition we observe an unusual regime where short-range tetratic correlations dominate over nematic correlations. This occurs due to the proliferation of Ising-like π2 grain boundaries that disrupt nematic order, but preserve tetratic correlations, at lengths shorter than the spacing between free disclinations.

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  • Received 9 April 2006

DOI:https://doi.org/10.1103/PhysRevE.76.040401

©2007 American Physical Society

Authors & Affiliations

Kun Zhao1, Christopher Harrison2, David Huse1, W. B. Russel3, and P. M. Chaikin4,*

  • 1Department of Physics, Princeton University, Princeton, New Jersey 08544, USA
  • 2Schlumberger-Doll Research Center, Ridgefield, Connecticut 06877, USA
  • 3Department of Chemical Engineering, Princeton University, Princeton, New Jersey 08544, USA
  • 4Center for Soft Condensed Matter Research, Department of Physics, New York University, New York, New York 10003, USA

  • *chaikin@physics.nyu.edu

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Vol. 76, Iss. 4 — October 2007

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