Exactly solvable disordered sphere-packing model in arbitrary-dimensional Euclidean spaces

S. Torquato and F. H. Stillinger
Phys. Rev. E 73, 031106 – Published 9 March 2006

Abstract

We introduce a generalization of the well-known random sequential addition (RSA) process for hard spheres in d-dimensional Euclidean space Rd. We show that all of the n-particle correlation functions of this nonequilibrium model, in a certain limit called the “ghost” RSA packing, can be obtained analytically for all allowable densities and in any dimension. This represents the first exactly solvable disordered sphere-packing model in an arbitrary dimension. The fact that the maximal density ϕ()=12d of the ghost RSA packing implies that there may be disordered sphere packings in sufficiently high d whose density exceeds Minkowski’s lower bound for Bravais lattices, the dominant asymptotic term of which is 12d. Indeed, we report on a conjectural lower bound on the density whose asymptotic behavior is controlled by 2(0.778 65)d, thus providing the putative exponential improvement on Minkowski’s 100-year-old bound. Our results suggest that the densest packings in sufficiently high dimensions may be disordered rather than periodic, implying the existence of disordered classical ground states for some continuous potentials.

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  • Received 15 September 2005

DOI:https://doi.org/10.1103/PhysRevE.73.031106

©2006 American Physical Society

Authors & Affiliations

S. Torquato*

  • Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA; Program in Applied and Computational Mathematics, Princeton University, Princeton New Jersey, 08544, USA; and PRISM, Princeton University, Princeton, New Jersey 08544, USA

F. H. Stillinger

  • Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA

  • *Electronic address: torquato@electron.princeton.edu

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Vol. 73, Iss. 3 — March 2006

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