Star polymers: A study of the structural arrest in the presence of attractive interactions

F. Lo Verso, L. Reatto, G. Foffi, P. Tartaglia, and K. A. Dawson
Phys. Rev. E 70, 061409 – Published 22 December 2004

Abstract

Simulations and mode-coupling theory calculations, for a large range of the arm number f and packing fraction η have shown that the structural arrest and the dynamics of star polymers in a good solvent are extremely rich: the systems show a reentrant melting of the disordered glass nested between two stable fluid phases that strongly resemble the equilibrium phase diagram. Starting from a simple model potential we investigate the effect of the interplay between attractive interactions of different range and ultrasoft core repulsion, on the dynamics and on the occurrence of the ideal glass transition line. In the two cases considered so far, we observed some significant differences with respect to the purely repulsive pair interaction. We also discuss the interplay between equilibrium and nonequilibrium phase behavior. The accuracy of the theoretical tools we utilized in our investigation has been checked by comparing the results with molecular dynamics simulations.

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  • Received 30 July 2004

DOI:https://doi.org/10.1103/PhysRevE.70.061409

©2004 American Physical Society

Authors & Affiliations

F. Lo Verso1,*, L. Reatto1, G. Foffi2, P. Tartaglia2, and K. A. Dawson3

  • 1Istituto Nazionale di Fisica della Materia and Dipartimento di Fisica, Università di Milano, Via Celoria 16, I-20133 Milano, Italy
  • 2Dipartimento di Fisica and INFM Center for Statistical Mechanics and Complexity, Università di Roma La Sapienza, Piazzale Aldo Moro 2, I-00185 Rome, Italy
  • 3Irish Center for Colloid Science and Biomaterials, Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland

  • *Electronic address: federica.loverso@mi.infn.it

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Vol. 70, Iss. 6 — December 2004

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