VO: A strongly correlated metal close to a Mott-Hubbard transition

F. Rivadulla, J. Fernández-Rossier, M. García-Hernández, M. A. López-Quintela, J. Rivas, and J. B. Goodenough
Phys. Rev. B 76, 205110 – Published 19 November 2007

Abstract

Here, we present experimental and computational evidences to support that rocksalt cubic VO is a strongly correlated metal with non-Fermi-liquid thermodynamics and an unusually strong spin-lattice coupling. An unexpected change of sign of metallic thermopower with composition is tentatively ascribed to the presence of a pseudogap in the density of states. These properties are discussed as signatures of the proximity to a magnetic quantum phase transition. The results are summarized in an electronic phase diagram for the 3d monoxides, which resembles that of other strongly correlated systems. The structural and electronic simplicity of 3d monoxides makes them ideal candidates to progress in the understanding of highly correlated electron systems.

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  • Received 9 May 2007

DOI:https://doi.org/10.1103/PhysRevB.76.205110

©2007 American Physical Society

Authors & Affiliations

F. Rivadulla1,*, J. Fernández-Rossier2, M. García-Hernández3, M. A. López-Quintela1, J. Rivas4, and J. B. Goodenough5

  • 1Physical-Chemistry Department, University of Santiago de Compostela, 15782 Santiago de Compostela, Spain
  • 2Applied Physics Department, University of Alicante, San Vicente del Raspeig, 03690 Alicante, Spain
  • 3Instituto de Ciencia de Materiales de Madrid (CSIC), Cantoblanco, E-28049 Madrid, Spain
  • 4Applied Physics Department, University of Santiago de Compostela, 15782 Santiago de Compostela, Spain
  • 5Texas Materials Institute, ETC 9.102, The University of Texas at Austin, 1 University Station, C2201, Austin, Texas 78712, USA

  • *qffran@usc.es

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Issue

Vol. 76, Iss. 20 — 15 November 2007

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