Comment on “Layering transition in confined molecular thin films: Nucleation and growth”

Saroj Kumar Nandi
Phys. Rev. B 74, 167401 – Published 4 October 2006

Abstract

When fluid is confined between two molecularly smooth surfaces to a few molecular diameters, it shows a large enhancement of its viscosity. From experiments it seems clear that the fluid is squeezed out layer by layer. A simple solution of the Stokes equation for quasi-two-dimensional confined flow, with the assumption of layer-by-layer flow is found. The results presented here challenge those of Persson and Tosatti [Phys. Rev. B. 50, 5590 (1994)] and show that both the kinematic viscosity of the confined fluid and the coefficient of surface drag can be obtained from the time dependence of the area squeezed out. Fitting our solution to the available experimental data gives a value of viscosity which is approximately seven orders of magnitude higher than that in the bulk.

    • Received 16 April 2006

    DOI:https://doi.org/10.1103/PhysRevB.74.167401

    ©2006 American Physical Society

    Authors & Affiliations

    Saroj Kumar Nandi*

    • Centre for Condensed Matter Theory, Department of Physics, Indian Institute of Science, Bangalore-560012, India

    • *Electronic address: snandi@physics.iisc.ernet.in

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    Original Article

    Layering transition in confined molecular thin films: Nucleation and growth

    B. N. J. Persson and E. Tosatti
    Phys. Rev. B 50, 5590 (1994)

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    Issue

    Vol. 74, Iss. 16 — 15 October 2006

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