Abstract
Recently, a new orthorhombic phase has been discovered in the ferroelectric system for and for after the application of an electric field. In the present work, synchrotron x-ray measurements have been extended to higher concentrations The orthorhombic phase was observed for but, surprisingly, for only a tetragonal phase was found down to 20 K. The orthorhombic phase thus exists only in a narrow concentration range with near-vertical phase boundaries on both sides. This orthorhombic symmetry type) is in contrast to the monoclinic -type symmetry recently identified at low temperatures in the (PZT) system over a triangle-shaped region of the phase diagram in the range To further characterize this relaxor-type system, neutron inelastic scattering measurements have also been performed on a crystal of with The anomalous soft-phonon behavior (“waterfall” effect) previously observed for and 8% is clearly observed for the 15% crystal, which indicates that the presence of polar nanoregions extends to large values of x.
- Received 17 August 2001
DOI:https://doi.org/10.1103/PhysRevB.65.144101
©2002 American Physical Society