Abstract
In this paper, we present a rich (4 strong first-order and an additional 98 weak lines) ir spectrum for a 4-μm-thick film on KBr in the range 400–4000 . Most of the weak lines are identified with second-order combination modes. More accurate frequencies of some optically inactive modes in have been obtained by simultaneously analyzing the higher-order ir and Raman spectra. Isotope-induced symmetry lowering in molecules has also been observed and is responsible for activating several fundamental modes which would otherwise be ir inactive.
- Received 1 June 1993
DOI:https://doi.org/10.1103/PhysRevB.48.11375
©1993 American Physical Society