Electronic properties of the metallic perovskite LaNiO3: Correlated behavior of 3d electrons

K. Sreedhar, J. M. Honig, M. Darwin, M. McElfresh, P. M. Shand, J. Xu, B. C. Crooker, and J. Spalek
Phys. Rev. B 46, 6382 – Published 1 September 1992; Erratum Phys. Rev. B 47, 5543 (1993)
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Abstract

Low-temperature electrical resistivity, specific heat, and magnetic measurements have been performed on the distorted perovskite LaNiO3. The electrical resistivity shows a linear temperature dependence at high temperatures and an AT2 dependence below ∼50 K. The static paramagnetic susceptibility is nearly Pauli-like with an additional small Curie-law contribution in the range 100–300 K, and shows stronger temperature dependence at lower temperatures. The specific heat can be represented as γTT3T3lnT at low temperatures. Both the Pauli magnetic susceptibility χ=5.1×104 emu/mol and the linear temperature coefficient of the specific heat γ=13.7 mJ/K2 mol are enhanced well above their electron gas values. The effective Stoner enhancement factor is S=0.58, i.e., far from the ferromagnetic instability. These results are interpreted in terms of a Fermi liquid composed of almost localized Ni 3d electrons. Thus, LaNiO3 represents a correlated metallic system.

  • Received 5 March 1992

DOI:https://doi.org/10.1103/PhysRevB.46.6382

©1992 American Physical Society

Erratum

Erratum: Electronic properties of the metallic perovskite LaNiO3: Correlated behavior of 3d electrons

K. Sreedhar, J. M. Honig, M. Darwin, M. McElfresh, P. M. Shand, J. Xu, B. C. Crooker, and J. Spalek
Phys. Rev. B 47, 5543 (1993)

Authors & Affiliations

K. Sreedhar and J. M. Honig

  • Department of Chemistry, Purdue University, West Lafayette, Indiana 47907

M. Darwin, M. McElfresh, P. M. Shand, J. Xu, B. C. Crooker, and J. Spalek

  • Department of Physics, Purdue University, West Lafayette, Indiana 47907

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Vol. 46, Iss. 10 — 1 September 1992

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