Abstract
Temperature () variations of the infrared molecular-vibration spectra of tetrathiafulvalene-chloranil (TTF-CA) crystalline powders have been measured at variable pressure (). From the observed behavior of the spectra as a function of and , it is concluded that both quasi-ionic and quasineutral molecules coexist in an intermediate range of and , until the crystal undergoes a phase transition to the dimerized ionic phase at which depends on . These results are discussed in terms of a phase diagram of TTF-CA crystal.
- Received 10 February 1987
DOI:https://doi.org/10.1103/PhysRevB.36.3884
©1987 American Physical Society