Atomic distortion and ac-Stark shifts of H under extreme radiation conditions

M. Pont
Phys. Rev. A 40, 5659 – Published 1 November 1989
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Abstract

According to a general nonperturbative theory that describes atomic behavior in intense, high-frequency radiation fields, the atom becomes stable against decay by multiphoton ionization in the limit of high frequencies if the parameter α0=(I/2)1/2ω2 (a.u.) (with I the intensity and ω the frequency of the field) is kept constant, although otherwise unrestricted. We show that, under this condition, in the subsequent limit of strong fields (α0 large), the Schrödinger equation describing the structure of the hydrogen atom in a laser field of circular polarization is separable in toroidal coordinates. Explicit asymptotic expressions are given for its energy eigenvalues and its eigensolutions. They correspond to a rapid decrease of the ionization potential and a drastic increase of the size of the atom with α0. For the binding energy of the ground state we find: ‖E0‖ =(1/2πα0) (lnα0+2.654284) (a.u.). A dramatic distortion of the shape of the atom is found, which in the strong field becomes a torus-shaped object. Furthermore, we introduce a classification of its states by strong-field quantum numbers. We show how the levels at low α0, characterized by the weak-field quantum numbers introduced earlier, and the levels at high α0, characterized by the strong-field quantum numbers, are correlated. We find that the energy spectrum in strong fields displays a multiplet structure. A comparison is made between our analytical results and those of a numerical calculation carried out earlier.

  • Received 5 July 1989

DOI:https://doi.org/10.1103/PhysRevA.40.5659

©1989 American Physical Society

Authors & Affiliations

M. Pont

  • Stichting voor Fundamenteel Onderzoek der Materie (FOM), Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands

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Issue

Vol. 40, Iss. 10 — November 1989

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