Relativistic-coupled-cluster-theory analysis of properties of Co-like ions

Dillip K. Nandy and B. K. Sahoo
Phys. Rev. A 104, 052812 – Published 19 November 2021

Abstract

Ionization potentials, excitation energies, transition properties, and hyperfine structure constants of the low-lying 3p63d92D5/2, 3p63d92D3/2, 3p53d102P3/2, and 3p53d102P1/2 atomic states of the Co-like highly charged ions such as Y12+, Zr13+, Nb14+, Mo15+, Tc16+, Ru17+, Rh18+, Pd19+, Ag20+, and Cd21+ are investigated. The singles and doubles approximated relativistic coupled-cluster theory in the framework of one electron removal Fock-space formalism is employed over the Dirac-Hartree-Fock calculations to account for the electron correlation effects for determining the aforementioned properties. Higher-order relativistic corrections due to the Breit interaction and quantum electrodynamics effects in the evaluation of energies are also quantified explicitly. Our estimated values are compared with the other available theoretical calculations and experimental results, which are found to be in good agreement with each other.

  • Figure
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  • Received 24 August 2021
  • Revised 1 November 2021
  • Accepted 3 November 2021

DOI:https://doi.org/10.1103/PhysRevA.104.052812

©2021 American Physical Society

Physics Subject Headings (PhySH)

Atomic, Molecular & Optical

Authors & Affiliations

Dillip K. Nandy1,* and B. K. Sahoo2,†

  • 1Center for Theoretical Physics of Complex Systems, Institute for Basic Science (IBS), Daejeon 34126, Korea
  • 2Atomic, Molecular and Optical Physics Division, Physical Research Laboratory, Ahmedabad-380009, India

  • *nandy@ibs.re.kr
  • bijaya@prl.res.in

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Issue

Vol. 104, Iss. 5 — November 2021

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