A Determination of the Total Electric Polarization and the Electric Moments of Certain Organic Molecules

Louis M. Heil
Phys. Rev. 39, 666 – Published 15 February 1932
PDFExport Citation

Abstract

An investigation has been made of the effect of temperature on the dielectric constants and densities of bromobenzene and iodobenzene in dilute solution with hexane and of hexane, and of m-p-o-xylenes as pure liquids.

The values of the electric moments and the validity of the Debye law: The values obtained for the electric moments are as follows; p-xylene, 0; m-xylene, 0.34×1018; o-xylene, 0.44×1018; bromobenzene, 1.35×1018; iodobenzene, 1.25×1018. In every case it was found that the Debye law, P=P0+aT, was valid.

Variation of the electric moment with variation of the atomic weight of a substituted atom; The results of this investigation give additional evidence of the rule that, as the atomic weight of a substituted atom is increased, the electric moment of the molecule decreases.

Change of induced polarization with the temperature. Evidence has been deduced which suggests that the induced polarization may be a function of the temperature and that this effect may neutralize or diminish the effect of a small dipole.

  • Received 14 September 1931

DOI:https://doi.org/10.1103/PhysRev.39.666

©1932 American Physical Society

Authors & Affiliations

Louis M. Heil

  • Mendenhall Laboratory of Physics, Ohio State University

References (Subscription Required)

Click to Expand
Issue

Vol. 39, Iss. 4 — February 1932

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review Journals Archive

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×