Abstract
An investigation has been made of the effect of temperature on the dielectric constants and densities of bromobenzene and iodobenzene in dilute solution with hexane and of hexane, and of m-p-o-xylenes as pure liquids.
The values of the electric moments and the validity of the Debye law: The values obtained for the electric moments are as follows; p-xylene, 0; m-xylene, 0.34×; o-xylene, 0.44×; bromobenzene, 1.35×; iodobenzene, 1.25×. In every case it was found that the Debye law, , was valid.
Variation of the electric moment with variation of the atomic weight of a substituted atom; The results of this investigation give additional evidence of the rule that, as the atomic weight of a substituted atom is increased, the electric moment of the molecule decreases.
Change of induced polarization with the temperature. Evidence has been deduced which suggests that the induced polarization may be a function of the temperature and that this effect may neutralize or diminish the effect of a small dipole.
- Received 14 September 1931
DOI:https://doi.org/10.1103/PhysRev.39.666
©1932 American Physical Society