Configurational Instability of Degenerate Electronic States

W. Moffitt and A. D. Liehr
Phys. Rev. 106, 1195 – Published 15 June 1957
PDFExport Citation

Abstract

The implications of the Jahn-Teller theorem are discussed with special reference to the case where the forces tending to lower the symmetry of electronically degenerate molecular states are of the same order as the restoring forces encountered during typical vibrations. It is shown that the resulting dynamical situation may be described as a particular kind of coupling between low-frequency electronic motions and nuclear modes.

  • Received 8 October 1956

DOI:https://doi.org/10.1103/PhysRev.106.1195

©1957 American Physical Society

Authors & Affiliations

W. Moffitt and A. D. Liehr

  • Department of Chemistry, Harvard University, Cambridge, Massachusetts

References (Subscription Required)

Click to Expand
Issue

Vol. 106, Iss. 6 — June 1957

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review Journals Archive

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×