Aggregation of colloids near a fluid membrane

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Published 22 January 2007 IOP Publishing Ltd
, , Citation A Bendouch et al J. Stat. Mech. (2007) P01016 DOI 10.1088/1742-5468/2007/01/P01016

1742-5468/2007/01/P01016

Abstract

The phase behaviour of a suspension of colloids near a soft interface is investigated. Particular emphasis is given to entropic interactions mediated by membrane fluctuations and their consequences on the local (re)organization of the suspension. In a generalized van der Waals description, the suspension undergoes a first-order phase transition where a dense phase of colloids coexists with a dilute one. We predict a decrease of the critical volume fraction compared to the value in the absence of fluctuation-induced interactions. These results highlight potential applications of entropic forces to control the thermodynamic state of a colloidal suspension.

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10.1088/1742-5468/2007/01/P01016