Brought to you by:

Critical nuclei for wetting and dewetting

, and

Published under licence by IOP Publishing Ltd
, , Citation R Bausch et al 1994 J. Phys. A: Math. Gen. 27 1405 DOI 10.1088/0305-4470/27/4/035

0305-4470/27/4/1405

Abstract

In a first-order wetting transition it is possible to overheat a microscopic layer from below to above the wetting temperature Tw, and to undercool a macroscopic layer from above to below Tw. In both cases the transition to stable equilibrium occurs by formation and growth of supercritical nuclei. The critical nuclei for overheating are droplets on the wall of the system and for undercooling they are dents in the macroscopic layer. A recent calculation of the critical droplet in a special dimension d0 is now supplemented by the calculation of the critical dent for dewetting. Although the analytic expressions for the profiles are closely related, the nuclei above Tw are finite whereas they are infinitely large below Tw. The latter is to be expected since the system is infinitesimally close to coexistence of wet and non-wet states at all temperatures T<Tw.

Export citation and abstract BibTeX RIS

Please wait… references are loading.
10.1088/0305-4470/27/4/035