HIGH DUST DEPLETION IN TWO INTERVENING QUASAR ABSORPTION LINE SYSTEMS WITH THE 2175 Å EXTINCTION BUMP AT z ∼ 1.4*

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Published 2010 November 12 © 2010. The American Astronomical Society. All rights reserved.
, , Citation Peng Jiang et al 2010 ApJ 724 1325 DOI 10.1088/0004-637X/724/2/1325

0004-637X/724/2/1325

ABSTRACT

We present the column densities of heavy elements and dust depletion studies in two strong Mg ii absorption systems at z ∼ 1.4 displaying the 2175 Å dust extinction feature. Column densities are measured from low-ionization absorption lines using an Apparent Optical Depth Method on the Keck/ESI spectra. We find that the dust depletion patterns resemble that of cold diffuse clouds in the Milky Way (MW). The values, [Fe/Zn] ≈−1.5 and [Si/Zn]<−0.67, are among the highest dust depletion measured for quasar absorption line systems. In another 2175 Å absorber at z = 1.64 toward the quasar SDSS J160457.50+220300.5, Noterdaeme et al. reported a similar dust depletion measurement ([Fe/Zn] = −1.47 and [Si/Zn] = −1.07) and detected C i and CO absorption lines on its VLT/UVES spectrum. We conclude that heavy dust depletion (i.e., a characteristic of cold dense clouds in MW) is required to produce a pronounced 2175 Å extinction bump.

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1. INTRODUCTION

Interstellar dust grains play an important role in the evolution of galaxies, star formation, and planet formation. The size distribution and composition of dust grains are mainly inferred from the observed extinction curve and the re-radiated infrared emission. So far, the best-studied interstellar extinction curves are the ones for the Milky Way (MW; Savage & Mathis 1979), the Large and Small Magellanic Clouds (LMC and SMC; Fitzpatrick 1989). The most conspicuous difference between them is the sequential increment in the strength of the 2175 Å extinction bump (Stecher 1965) from SMC to LMC to MW. The feature is rarely seen in other local galaxies (Keel & White 2001).

Wang et al. (2004) composed a comprehensive review on the detection of the 2175 Å absorption bump in quasar absorption line (QAL) systems (see also references therein) and reported three bumps at high redshift z ∼ 1.4. The 2175 Å absorber in several cases (Cohen et al. 1999; Wucknitz et al. 2003) were confirmed to be damped Lyα absorbers (DLAs). Recently, several new detections have been reported. Srianand et al. (2008) found a 2175 Å extinction feature in two Mg ii systems at z ∼ 1.3 and detected associated 21 cm absorption, which usually traces cold gas content. Noterdaeme et al. (2009) presented a detection of carbon monoxide molecules (CO) at z = 1.6408 toward a red quasar and a pronounced 2175 Å bump at the same redshift. A super-strong 2175 Å absorption galaxy at z = 0.8839 toward the quasar SDSS J100713.68+285348.4 was reported by Zhou et al. (2010). Besides the quasar absorption approach to search for the 2175 Å dust extinction feature in high-redshift galaxies, the analysis of gamma-ray burst (GRB) afterglow spectra has also revealed several positive detections from intervening absorbers and from gas in the GRB host galaxy (e.g., Ellison et al. 2006; Elíasdóttir et al. 2009; Prochaska et al. 2009).

The physical conditions of absorbers, such as ionization state, electron density, temperature, gas kinetics, metallicity, and dust depletion, can be measured from the relative strength and the profile of metal absorption lines (e.g., Pettini et al. 1994; Prochaska & Wolfe 1998; Jenkins & Tripp 2001; Prochaska et al. 2002). The measurements of metal absorption lines associated with very rare 2175 Å quasar absorbers can definitely help us to understand the physical characteristics giving rise to the dust extinction features at high redshift (i.e., z > 1.0). In this paper, we analyze the dust depletion levels of the two 2175 Å absorbers in lines of sight toward the quasars SDSS6 J012147.73+002718.7 (hereafter J0121+0027; z = 2.2241) and SDSS J145907.19+002401.2 (hereafter J1459+0024; z = 3.0124).

Dust depletion in MW has been widely studied over ∼240 sight lines in the past several decades with the ultraviolet (UV) space telescopes (e.g., Jenkins 2009 and references therein). Significant deviation of depletion levels in different Galactic environments is found. Generally speaking, heavy elements are more depleted onto dust grains in cold gas clouds than in warm and halo gas clouds (e.g., Sembach & Savage 1996; Welty et al. 1997, 1999). Comparing the dust depletion patterns of the 2175 Å absorbers with the Galactic clouds can provide important clues on the general astrophysical characteristics of them. The dust depletion for the two absorbers in this work is very similar to that measured in cold clouds of MW, which are characterized by cold, dense, and primarily molecular gas. Dust depletion is also usually used to identify the dust content in DLAs (e.g., Pettini et al. 1994, 1997, 1999; Lu et al. 1996).

This paper is organized as follows. In Section 2 we describe the observations, Section 3 presents the analysis of UV extinction bumps, in Section 4 we present the measurements of elemental column densities in the two absorption line systems, in Section 5 we explore the dust depletion patterns, discussions are presented in Section 6, and future work and conclusions are given in Section 7.

2. OBSERVATIONS

The Sloan Digital Sky Survey (SDSS) spectra of these two quasars are remarkable with depressed flux around ∼5500 Å. They were initially uncovered by Patrick B. Hall when he carried out a visual inspection of the SDSS spectra of the DR1 quasars with z ⩾ 1.6 (Schneider et al. 2003) to identify unusual quasar subtypes (i.e., primarily broad absorption line quasars, nitrogen-strong quasars, and dust reddened quasars). The features were then interpreted as 2175 Å extinction bumps associated with two strong intervening Mg ii absorbers at z∼ 1.4 in lines of sight toward the quasars by Wang et al. (2004).7 The point-spread function magnitudes measured from the SDSS images are u = 20.68 ± 0.06, g = 19.09 ± 0.01, r = 18.46 ± 0.01, i = 17.93 ± 0.01, and z = 17.65 ± 0.02 for J1459+0024; u = 20.44 ± 0.06, g = 19.97 ± 0.02, r = 19.38 ± 0.01, i = 19.03 ± 0.02, and z = 18.70 ± 0.04 for J0121+0027, respectively. The SDSS spectra cover ∼3800–9200 Å with a spectral resolution R ∼ 2000 (Stoughton et al. 2002).

We performed follow-up spectroscopic observations of the quasars at higher spectral resolution to explore the dust depletion in these two 2175 Å absorbers. The medium-resolution (R ∼ 10, 000), medium signal-to-noise ratio (S/N ⩾ 10) quasar spectra were obtained with the 10 m Keck telescope using the Echellette Spectrographs and Imager (ESI; Sheinis et al. 2002). The entire spectra cover the full optical range from 3900 Å to 1.1 μm, recorded by a single 2K × 4K Lincoln Labs CCD with 15 μm pixels. The quasars were observed on 2003 December 20 (UT) with total exposure times of 900 s and 2700 s for J1459+0024 and J0121+0027 under good conditions but variable seeing of approximately full width at half-maximum (FWHM) = 0farcs8. We implemented the 0farcs5 slit for J1459+0024 and the 0farcs75 slit for J0121+0027 which yields an FWHM resolution of 33 km s−1 and 44 km s−1, respectively. An additional 1800 s exposure for J1459+0024 was obtained on 2004 February 18 (UT). The data were reduced and calibrated using the ESIRedux software package (v1.0) developed by JXP (see Prochaska et al. 2003 for details). Then the two reduced spectra of J1459+0024 were combined. The data were normalized by fitting a series of polynomials to absorption-free regions of the quasar spectrum.

3. 2175 Å EXTINCTION BUMPS

Jiang et al. (2010) used a parameterized extinction curve (FM parameterization; Fitzpatrick & Massa 1990) constituted by a linear component and a Drude component to describe the optical/UV extinction curve in the rest frame of the quasar absorber. The linear component is used to model the underlying extinction,8 while the Drude component is used to model the possible 2175 Å extinction bump. The parameterized extinction curve is written as

Equation (1)

where x = λ−1 and D(x, x0, γ) is a Drude profile, which is expressed as

Equation (2)

where x0 and γ are the peak position and FWHM of the Drude profile, respectively. Our aim is to unveil the 2175 Å absorption feature associated with absorption line systems on quasar spectra. We do not try to derive the absolute extinction curve. Our derived curve is a relative extinction curve without being normalized by E(BV). We cannot measure the conventional extinction parameters AV, E(BV), and RV from it. But all the features of the 2175 Å absorption bump are preserved. The strength of the bump is measured by the area of the bump Abump = πc3/(2γ), which can be interpreted as rescaling the integrated apparent optical depth of bump absorption ($A_{\lambda }={\frac{2.5}{{\rm ln} 10}}\tau _{\lambda }$). We fit the SDSS spectra of J1459+0024 and J0121+0027 by reddening the SDSS composite quasar spectrum (Vanden Berk et al. 2001) with parameterized extinction curves at the redshifts zabs = 1.3947 for the former and zabs = 1.3888 for the latter, respectively. The redshifts are those of the strongest component in the absorption line profiles, which are measured on our Keck/ESI spectra, for the two 2175 Å absorbers. Since the 2175 Å extinction bump is a very broad feature whose FWHM is usually greater than 300 Å (Fitzpatrick & Massa 2007), the small differences between these redshifts and the redshifts of the centroid of absorption line profiles could not affect the results of spectrum fitting in this work. To focus on fitting the continuum of quasar spectrum, the regions with strong emission lines and known strong absorption lines are masked. Several intervening Lyα absorption lines are present blueward of the Lyα emission lines on the spectrum of J1459+0024 with z > 2.6. We remove them iteratively by clipping the outliers beyond 4σ error. The results of spectrum fitting are listed in Table 1. The best models are overplotted with SDSS data in Figures 1(a) and 2(a). To emphasize the requirement of a absorption bump on the extinction curve, we also overplot the reddened composite quasar spectrum by using the linear component of best model (green lines in Figures 1(a) and 2(a)) only. The required bump of J1459+0024 is so broad that its wings exceed the wavelength coverage of the SDSS spectrum. Thus, the entire observed spectrum of J1459+0024 is completely off from the green model in Figure 1(a).

Figure 1.

Figure 1. Best-fit extinction model for J1459+0024. (a) Red solid line is the best-fit model. Red arrow indicates the center of extinction bump and blue arrow indicates the Mg ii absorption lines. Green solid line is reddened composite quasar spectrum by using the linear component of best model only to emphasize the requirement of extinction bump. (b) The best-fit extinction curve (see the parameters of extinction curves in Table 1). (c) Distribution of the fitted bump strength of the control sample for J1459+0024. The blue line is the best-fit Gaussian profile. Red arrow indicates the strength of the bump on the spectrum of J1459+0024.

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Figure 2.

Figure 2. Best-fit extinction model for J0121+0027. (a) Red solid line is the best-fit model. Green solid line is reddened composite quasar spectrum by using the linear component of best model only. (b) The best-fit extinction curve. (c) Distribution of the fitted bump strength of the control sample for J0121+0027. Red arrow indicates the strength of bump on the spectrum of J0121+0027.

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Table 1. Parameters of Optical/UV Extinction Curves

Reddened Object c1 c2 c3 x0 γ E(BV) RV χ2ν
J1459+0024 −2.17 ± 0.02 0.08 ± 0.01 9.22 ± 0.71 4.56 ± 0.02 2.68 ± 0.07     2.19
J0121+0027 −0.65 ± 0.02 0.06 ± 0.01 0.48 ± 0.04 4.64 ± 0.01 0.80 ± 0.04     1.08
HD 29647 −0.77 ± 0.18 0.79 ± 0.03 10.67 ± 2.79 4.639 ± 0.037 2.41 ± 0.22 0.96 ± 0.02 3.46 ± 0.09  
HD 164816 1.14 ± 0.39 0.45 ± 0.06 2.07 ± 0.12 4.602 ± 0.004 0.78 ± 0.02 0.29 ± 0.01 3.26 ± 0.18  

Notes. Best-fitted parameters of extinction curves for the two absorbers. The parameters for reddened Galactic stars are adopted from Fitzpatrick & Massa (2007). The parameters c1, c2, and c3 for the absorbers are not normalized by E(BV) and AV, while the relevant parameters for the Galactic stars are normalized values.

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The intrinsic variation of quasar spectra can mimic an extinction bump in some cases (Pitman et al. 2000). We gauge the significance of the extinction bumps in this work with the simulation technique developed by Jiang et al. (2010). The simulation technique begins with the selection of a control sample of SDSS quasar spectra at a similar redshift to the quasar of interest. Then we fit each of them by reddening the composite quasar spectrum with a parameterized extinction curve at the redshift of the absorber of interest. The parameters x0 and γ in the parameterized extinction curve are fixed to the best values fitting the 2175 Å extinction bump of interest. The distribution of bump strengths is expected to be Gaussian by assuming random fluctuation of continuum on each spectrum in the control sample. If the bump strength of the absorber is far away from this distribution, then the bump has statistical significance. For each quasar, we select the spectra in the SDSS DR7 database classified as quasars (specClass = QSO or HIZ_QSO) with redshift in the range of zemi − 0.05 < z < zemi + 0.05 and S/N SN_I ⩾ 6,9 as its control sample. The resultant control sample of J1459+0024 is constituted by 1002 SDSS quasars around z = 3.0124. The resultant control sample of J0121+0027 is constituted by 2351 SDSS quasars around z = 2.2241. The extracted distributions of bump strengths are presented in Figures 1(c) and 2(c). Both of the bumps in J1459+0024 and J0121+0027 are statistically significant at a confidence level of >5σ. The width of the bump strength distribution for J1459+0024 is much greater than that for J0121+0027. That is because the bump on the spectrum of J1459+0024 (γ = 2.68 μm−1) is much broader than that of J0121+0027 (γ = 0.80 μm−1). For the spectrum without a real extinction feature, the fitted bump strength is an integration of random fluctuations over the wavelength range covered by the bump of interest. In principle, a longer integration makes the resultant distribution of bump strengths broader. Therefore, a broad bump has to be stronger (with larger bump area) than a narrow one in order to be significantly distinguished from random fluctuations of quasar spectra. In theory, the mean value of the bump strength distribution should be zero. But, the mean value of the bump strength distribution is about 1.0 for J1459+0024 (see Figure 1(c)). The significant non-zero mean bump strength is mainly caused by the low quality of the SDSS quasar composite spectrum in far-UV band of its rest frame. There are only about 150 low (or moderate) observed quasar spectra being used to create the composite spectrum in far-UV band (Vanden Berk et al. 2001).10 Thus, it is very likely that the composite quasar spectrum cannot represent the average properties of quasar spectra in far-UV band completely.

We also perform continuum fitting by reddening the SDSS composite spectrum with different types of average extinction curves, namely that from the SMC, the LMC Supershell (LMC2), the LMC (Gordon et al. 2003), and the MW (Fitzpatrick & Massa 2007). The 2175 Å extinction bump is absent in the SMC extinction curve and it is strongest in the LMC and the MW extinction curves. The strength of the bump in the LMC2 extinction curve is medium. These extinction curves are given in the FM parameterization. The two free parameters in the continuum fitting are E(BV) and a normalization scale. The results of spectrum fitting are presented in Table 2. We show the models using different extinction curves for the two reddened quasar spectra in Figure 3. The spectrum of J0121+0027 can be fitted by the average LMC (χ2ν = 1.14) and the average MW (χ2ν = 1.10) extinction curve models. But the spectrum of J1459+0024 cannot be fitted by any model (χ2ν = 3.88 in the best case). That is because the extinction bump on J1459+0027 is much broader (γ = 2.68 ± 0.07 μm−1) than that of the average LMC (γ = 0.934 ± 0.016 μm−1) extinction curve or the average MW (γ = 0.922 μm−1) extinction curve.

Figure 3.

Figure 3. Fitting the reddened quasar spectra by reddening the SDSS composite quasar spectrum with different extinction curves. Green spectra are for the average SMC extinction curve; blue spectra are for the average LMC Supershell (LMC2) extinction curve; yellow spectra are for the average LMC extinction curve; red spectra are for the average MW extinction curve. Left panel presents the models for J1459+0024 and right panel presents the models for J0121+0027.

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Table 2. Results of Fitting SDSS Spectra with Different Extinction Curves

Extinction Law E(BV) E(BV) χ2ν χ2ν
  (J1459) (J0121) (J1459) (J0121)
SMC 0.21 ± 0.01 0.11 ± 0.01 6.34 1.69
LMC2 0.29 ± 0.01 0.17 ± 0.01 4.26 1.28
LMC 0.25 ± 0.01 0.14 ± 0.01 3.88 1.14
MW 0.26 ± 0.01 0.15 ± 0.1 3.93 1.10

Notes. Results of fitting the spectra by reddening the SDSS composite quasar spectrum with the average extinction curves of SMC Bar, LMC2, LMC, and MW. The average extinction curves of SMC, LMC2, and LMC are adopted from Gordon et al. (2003); the average extinction curve of MW is adopted from Fitzpatrick & Massa (2007).

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We compare the two extracted 2175 Å absorption bumps at z∼ 1.4 with the bumps observed in the MW (see Figure 4; Fitzpatrick & Massa 2007). The peak position and strength of bumps are within the range of Galactic values. However, the FWHM of bump in J1459+0024 is larger than the broadest Galactic bump, which is measured in the line of sight toward the star HD 29647. The direct comparison of Optical/UV extinction curves of J1459+0024 and HD 29647 is plotted in Figure 4(c) and the comparison of J0121+0027 and HD 164816 (the latter has a similar bump with the former) is in Figure 4(d). Since the extracted extinction curves for quasar absorbers are relative extinction curves, we cannot measure the absolute visual extinction AV on them. We add an arbitrary normalization on the extracted curves while plotting them with Galactic curves.

Figure 4.

Figure 4. Comparisons of extinction bump parameters with the 328 Galactic values measured toward stars from Fitzpatrick & Massa (2007). (a) The distribution of peak position and width of the bumps. The width of the bump in J1459+0024 is broader than the broadest Galactic bump in the line of sight toward star HD 29647. (b) Histogram of bump strength measured toward Galactic stars. Red arrow indicates the strength of the bump in J0121+0027 and blue arrow indicates the strength of the bump in J1459+0024. (c) Direct comparison of derived Optical/UV extinction curve of J1459+0024 with the curve measured in the line of sight toward star HD 29647. (d) Direct comparison of the derived UV extinction curve of J0121+0027 with the curve measured in the line of sight toward star HD 164816 (see the parameters of extinction curves in Table 1). An arbitrary normalization is added to our relative extinction curve when plotting.

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4. MEASUREMENTS OF COLUMN DENSITIES

The total number of absorption components is not fully resolved because of our limited resolution and the intrinsic line-blending. For the line of sight toward J0121+0027, three Mg ii absorption systems are seen at z = 1.3877, 1.3888, and 1.3907, which match the approximate redshift of the 2175 Å absorption bump (z∼ 1.39; Wang et al. 2004) detected in the SDSS spectrum. Since the first two strong systems are only separated by ∼140 km s−1 (corresponding to z = 1.3888), they are considered as two associated components in one absorption system at z = 1.3888 in this work. The third one could be another component, but it is neglected in our analysis because it is too weak to affect the measurements. For the line of sight toward J1459+0024, one strong Mg ii absorption system is seen at z = 1.3947. We identified numerous absorption lines associated with the absorption system, consistent with the 2175 Å absorption bump feature redshift (z∼ 1.39) measured in the SDSS spectrum. The metal absorption lines of interest are plotted in velocity space in Figures 5 and 6.

Figure 5.

Figure 5. Velocity plots of the metal line transitions for absorption system at z = 1.3947 toward quasar J1459+0024. The vertical thick blue dash lines correspond to velocity = 0 km s−1 at that redshift.

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Figure 6.

Figure 6. Velocity plots of the metal line transitions for absorption system at z = 1.3888 toward quasar J0121+0027. The vertical thick blue dash lines correspond to velocity = 0 km s−1 at that redshift. The thin blue dot lines correspond to velocity = −70 km s−1 at z = 1.3888 to separate the two velocity components.

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We carry out the Apparent Optical Depth Method (AODM; Savage & Sembach 1991) to measure the column densities of low-ionization absorption lines in those two 2175 Å absorption systems. In general, the column densities are measured by integrating the optical depth over the velocity range of the spectra covering all of the absorption in the detected transitions. The uncertainties for detections are reported as 1σ errors. The upper limits are measured by integrating the optical depth over the same velocity range as an unsaturated line (i.e., Fe ii λ2374) and are reported as 3σ statistical limits. For the saturated lines, the column densities derived from the AODM are reported as lower limits. We also measured the column densities of transitions in red and blue components of the absorption system toward J0121+0027 separately. The boundary of these two components is chosen at the point of −70 km s−1 compared to redshift z = 1.3888 (the thin blue dot line in Figure 6). All ionic column densities are presented in Table 3.

Table 3. Measurements of Column Densities

λvacuum Ion f NXa NXb NXc NXd
(Å)     log(cm−2) log(cm−2) log(cm−2) log(cm−2)
1741.5531 Ni ii 0.0427 ...e <14.42 <14.30 <14.13
1808.0130 Si ii 0.0022 <15.46 15.59 ± 0.13 15.22 ± 0.21 15.35 ± 0.17
1854.7164 Al iii 0.5390 <13.81 13.71 ± 0.06 13.03 ± 0.09 13.61 ± 0.06
1862.7895 Al iii 0.2680 <13.49 13.55 ± 0.09 12.94 ± 0.19 13.43 ± 0.09
2026.1360 Zn ii 0.4890 13.12 ± 0.06 13.26 ± 0.08 12.94 ± 0.10 12.98 ± 0.10
2056.2539 Cr ii 0.1050 <13.81 <13.33 <13.28 <13.20
2062.6640 Zn ii 0.2560 13.22 ± 0.08 13.45 ± 0.09 13.19 ± 0.11 13.12 ± 0.13
2066.1610 Cr ii 0.0515 <13.61 <13.89 <13.73 <13.68
2344.2140 Fe ii 0.1140 >14.50 >14.69 >14.29 >14.48
2374.4612 Fe ii 0.0313 14.61 ± 0.05 14.82 ± 0.05 14.36 ± 0.06 14.64 ± 0.06
2382.7650 Fe ii 0.3200 >14.15 >14.41 >14.09 >14.13
2576.8770 Mn ii 0.3508 13.02 ± 0.06 13.07 ± 0.06 12.55 ± 0.10 12.92 ± 0.07
2586.6500 Fe ii 0.0691 14.46 ± 0.05 14.70 ± 0.05 14.31 ± 0.05 14.47 ± 0.05
2594.4990 Mn ii 0.2710 13.00 ± 0.07 12.80 ± 0.11 12.11 ± 0.42 12.70 ± 0.11
2600.1729 Fe ii 0.2390 >14.25 >14.44 >14.14 >14.13
2606.4620 Mn ii 0.1927 13.07 ± 0.08 12.83 ± 0.14 12.44 ± 0.26 12.60 ± 0.18
2796.3520 Mg ii 0.6123 >14.03 >14.42 >14.09 >14.14
2803.5310 Mg ii 0.3054 >14.26 >14.65 >14.25 >14.43
2852.9642 Mg i 1.8100 12.67 ± 0.05 12.91 ± 0.05 12.53 ± 0.05 12.68 ± 0.05
3384.7400 Ti ii 0.3580 <12.50 <12.54 <12.35 <12.36

Notes. Vacuum wavelengths and oscillator strength f are adopted from the Atomic Data conducted by J. X. Prochaska (http://www.astro.ufl.edu/~jpaty/qal.lst). The systematic error of column densities can exceed 0.05 dex due to continuum fitting and line saturation with ESI data. We combine the photon noise error and the estimated systematic error quadratically as reported error. aAbsorption lines system at z = 1.3947 toward the QSO J1459+0024. bAbsorption lines system at z = 1.3888 toward the QSO J0121+0027. cThe blue component in profiles of absorption lines toward the QSO J0121+0027. dThe red component in profiles of absorption lines toward the QSO J0121+0027. eNi ii 1741 absorption line in J1459+0024 system is blended with an unidentified absorption feature (see Figure 5). Its column density cannot be measured.

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5. DUST DEPLETION PATTERNS

The column density measurements of ions from absorption lines only represent the elements in the gas phase. If one assumes that ionization corrections are small for what is expected to be a primarily neutral gas, the observed relative gas-phase abundances reflect the underlying nucleosynthetic abundance pattern modified by the differential depletion of the elements. Frequently, the relative abundance, [Fe/Zn] = log(N(Fe)/N(Zn))−log(N(Fe)/N(Zn)),11 is used to infer the dust depletion level, even when N(H i) is not obtainable, by assuming that Zn, which is assumed to be nearly undepleted due to its low condensation temperature (Meyer & Roth 1990; Pettini et al. 1994), tracks the Fe Peak closely in nucleosynthesis.

The detected transitions of zinc are Zn ii λ2026 and Zn ii λ2062 on our Keck spectra. These two absorption lines are weakly blended with Mg i λ2026 and Cr ii λ2062 lines, respectively. Since the oscillator strength of transition Cr ii λ2062 is fairly weak and other transitions of Cr ii are only marginally detected in both of the absorption systems, we think the absorption line of Zn ii λ2062 is not contaminated by blending and take the column density of zinc measured on it to derive dust depletion patterns. For other species, the weighted mean values are adopted if there are two or more transitions detected. The depletion patterns are listed in Table 4.

Table 4. Measurements of Dust Depletion Levels

Species J1459 J0121a J0121b J0121c Coldd Warmd Halod LMCe SMCf
        [X/Zn]          
Si <−0.67 −0.77 ± 0.16 −0.88 ± 0.24 −0.68 ± 0.21 −0.9 −0.2 −0.2 <+0.32 +0.07
Mn −0.99 ± 0.10 −1.22 ± 0.11 −1.46 ± 0.12 −1.05 ± 0.15 −1.0 −0.7 −0.5 −0.50 −0.46
Mg >−1.89 >−1.73 >−1.87 >−1.62 −0.8 −0.4  ⋅⋅⋅  ⋅⋅⋅  ⋅⋅⋅
Fe −1.58 ± 0.09 −1.58 ± 0.10 −1.72 ± 0.12 −1.45 ± 0.14 −1.8 −1.2 −0.5 −1.12 −0.57
Cr <−0.65 <−0.60 <−0.50 <−0.48 −1.7 −1.0 −0.5 −0.76 −0.50
Ni  ⋅⋅⋅ <−0.66 <−0.52 <−0.62 −2.1 −1.5 −0.7 −1.46 −1.09
Ti <−1.02 <−1.21 <−1.14 <−1.06 −2.5 −1.1 −0.7 −1.35  ⋅⋅⋅

Notes. The solar photospheric values are adopted from Asplund et al. (2005). aDepletion in overall profiles of absorption lines toward the QSO J0121+0027. bDepletion in the blue component in profiles of absorption lines toward the QSO J0121+0027. cDepletion in the red component in profiles of absorption lines toward the QSO J0121+0027. dDepletion in cold disk clouds, warm disk clouds, and diffuse halo clouds (Jenkins et al. 1986; Welty et al. 1999, 2001). eDepletion in LMC ISM in line of sight toward SN 1987A (Welty et al. 1999). fDepletion in SMC ISM in line of sight toward star SK108 (Welty et al. 1997).

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We compare the dust depletion patterns in the two 2175 Å absorption systems with the depletion patterns observed in SMC ISM, LMC ISM, and cold Galactic disk clouds (Welty et al. 1997, 1999) in Figure 7. The dust depletion levels increase sequentially from SMC, LMC, to MW. It is clear that the depletion patterns of both absorption systems closely resemble that in cold Galactic clouds, especially from the best measured [Fe/Zn] values. The strength of the 2175 Å extinction bumps increases in the same manner as dust depletion from SMC, LMC, to MW. It is very likely that heavy dust depletion is required to give rise to 2175 Å absorption. See more discussions in Section 6.

Figure 7.

Figure 7. Dust depletion patterns in the two 2175 Å absorbers are compared with those measured in the ISM of the local group. The blue dots are the relative abundances of the absorption system toward the quasar J1459+0024. The red dots are the relative abundances (over the whole absorption line profile) toward the quasar J0121+0027. The empty squares are dust depletion patterns measured in SMC ISM; the black filled circles are patterns in LMC ISM; the empty triangles are patterns in cold Galactic disk clouds (Welty et al. 1997, 1999).

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The depletion levels, [Fe/Zn] ≈−1.5 and [Si/Zn] <−0.67, in both of absorbers are among the highest dust depletion ever measured for QAL systems. The mean value of [Fe/Zn] > − 0.6 was measured by York et al. (2006) with a large sample constituted by 809 Mg ii absorption systems at 1 ⩽ z < 2. A comparable depletion measurement with ours has been reported by Petitjean et al. (2002) in a DLA bearing molecular hydrogen with [Fe/Zn] = −1.59 at z = 1.973 toward the quasar Q0013-004. In addition, Noterdaeme et al. (2009) measured a similar high dust depletion level ([Fe/Zn] = −1.47 and [Si/Zn] = −1.07) of a 2175 Å absorber at z = 1.64 toward the quasar SDSS J160457.50+220300.5 with VLT/UVES. We compare the dust depletion level in this work with a combined DLA/sub-DLA sample, for which high-resolution spectroscopic data are available (Keck/ESI and Keck/HIRES data from Prochaska et al. 2007; VLT/UVES data from Noterdaeme et al. 2008), in Figure 8. We ignore censored data in the sample when plotting the figure. To present the dust depletion of two 2175 Å absorbers in the same figure, we assume the column density of neutral hydrogen N(H i) = 1021 cm−1 in both of them. This assumption is arbitrary and is for illustration purposes only. DLAs bearing H2 are marked with black filled circles. It is clear that DLAs showing high dust depletion level, [Fe/X]12<−0.4, have a high H2 detection rate (e.g., Ge & Bechtold 1997; Ge et al. 2001; Ledoux et al. 2003; Cui et al. 2005; Noterdaeme et al. 2008). It is reasonable to assume, therefore, that the gas in these two 2175 Å absorbers bears molecules.

Figure 8.

Figure 8. Comparison of dust depletion ([Fe/Zn] and [Si/Zn]) in this work with that in a DLA/sub-DLA sample. The empty circles are measurements in a combined DLA/sub-DLA sample having high-resolution spectra (Prochaska et al. 2007 and Noterdaeme et al. 2008), while the black filled circles are for H2-bearing DLAs in the subsample from Noterdaeme et al. (2008). N(H i) = 1021 cm−1 is assumed in both of the 2175 Å absorbers arbitrarily for illustration purposes only.

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6. DISCUSSION

The dust depletion patterns ([X/Zn]) in the SMC ISM are very similar to that measured in Galactic halo clouds, while the depletion in the LMC ISM is very similar to that in Galactic warm disk clouds (see Table 4). Since the overall metallicity and dust-to-gas ratio are very different in SMC, LMC, and MW (e.g., Pei 1992; Welty et al. 1997), the similarities probably indicate that dust depletion can hardly be dependent on these two physical parameters. In the MW, the most severe depletions are found in lines of sight with the largest mean densities and largest fraction of H2; the least severe depletions are observed for halo clouds and for high-velocity clouds in the Galactic disk (e.g., Jenkins et al. 1984; Savage & Sembach 1996; Fitzpatrick 1996; Trapero et al. 1996; Jenkins & Wallerstein 1996; Welty et al. 1997). Such a dependence of dust depletion on environment probably has to do with the modification or destruction of dust grains by supernova shocks. In cold dense molecular clouds, large dust grains can form substantially by coagulation of finer grains, while in warmer environments, large grains are usually destroyed by energetic processes and some depleted elements return to the gas phase.

The fact that the strength of 2175 Å extinction bumps becomes weaker with decreasing dust depletion levels from MW, LMC, to SMC may indicate, that the destruction of 2175 Å absorption carriers happens simultaneously with the destruction of large grains. The large polycyclic aromatic hydrocarbon (PAH) molecules, which have strong π → π* absorption in the 2000–2500 Å region, are proposed to be the carrier of 2175 Å absorption (Li & Draine 2001). These large molecules can be easily destroyed by photon-thermo dissociation, coulomb explosion, and/or X-ray destruction (e.g., Voit 1992 and references therein).

We search for the literatures and find 15 lines of sight in MW having both measurements of UV absorption bump and metal abundance available (see Table 5). Dust depletion is measured with the abundance ratio [Fe/H] by assuming that the underlying abundances are solar values. The measurements of Galactic 2175 Å extinction bump are taken from Fitzpatrick & Massa (2007). Note that the area of the bump defined in FM07 is different from that defined in this work. Since the extinction curve has been normalized by E(BV) in FM07, Abump = E(BV)×A*bump, where A*bump is the area defined in FM07. We plot the relative bump strength ($\frac{A_{\rm bump}}{A_V}$) versus [Fe/H] in Figure 9(a). We calculate Spearman's ρ, a non-parametric measure of statistical dependence between two variables, for the relative strength of the bump and [Fe/H]. The resultant Spearman's ρ = −0.46 suggests a tentative anti-correlation between them with statistical confidence level of 90%. The fairly large scatter of bump strength could be caused by the varying size of PAH molecules from one sightline to another. Draine (2003) interpreted that the observed variations in FWHM (and small variations in peak position) of the Galactic 2175 Å extinction bump profile resulted from differences in the PAH mix. This differences could also affect the oscillator strength per molecule and lead to the deviation of bump strengths. Note that the two 2175 Å extinction bumps in this work have very different widths and strengths.

Figure 9.

Figure 9. Dust depletion and dust extinction features in 15 lines of sight in MW. (a) A tentative anti-correlation between the dust depletions ([Fe/H]) and the relative bump strengths (Spearman's ρ = −0.46). (b) A tentative correlation between the fractions of molecular hydrogen (f (H2)) and the relative bump strengths (Spearman's ρ = +0.31). (c) A moderate anti-correlation between [Fe/H] and f (H2) in the Galactic clouds (Spearman's ρ = −0.81). (d) A tentative correlation between [Fe/H] and dust-to-gas ratio (AV/N(Htot); Spearman's ρ = 0.54). The dash line indicates the average Galactic dust-to-gas ratio (Bohlin et al. 1978).

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Table 5. Fe ii Abundance and Extinction Parameters in MW

Star N(Htot)a f (H2) N(Fe ii)b RV E(BV) c3 γ Reference
  log(cm−2)   log(cm−2)   (mag)   (μm−1)  
(1) (2) (3) (4) (5) (6) (7) (8) (9)
HD 12323 21.29 0.22 15.16+0.07−0.07 2.90 ± 0.26 0.21 ± 0.01 3.04 ± 0.24 0.86 ± 0.02 2,3,4
HD 37903 21.50 0.53 14.87+0.12−0.10 3.95 ± 0.21 0.33 ± 0.01 2.21 ± 0.13 0.92 ± 0.02 2,3,4
HD 40893 21.59 0.19 15.32+0.06−0.05 2.71 ± 0.13 0.45 ± 0.01 2.35 ± 0.08 0.82 ± 0.01 2,3,4
HD 73882 21.59 0.67 15.29+0.06−0.04 3.45 ± 0.08 0.67 ± 0.01 2.71 ± 0.10 1.12 ± 0.02 2,3,4
HD 91651 21.16 0.02 15.37+0.03−0.03 3.49 ± 0.22 0.28 ± 0.01 2.69 ± 0.26 1.03 ± 0.05 2,3,4
HD 93222 21.42 0.04 15.55+0.08−0.07 5.05 ± 0.20 0.33 ± 0.01 1.94 ± 0.10 0.79 ± 0.02 2,3,4
HD 104705 21.17 0.13 15.40+0.02−0.08 4.34 ± 0.20 0.28 ± 0.01 2.15 ± 0.13 0.80 ± 0.01 2,3,4
HD 147888 21.76 0.10 15.50+0.03−0.02 4.08 ± 0.13 0.51 ± 0.01 2.50 ± 0.11 0.89 ± 0.02 2,3,4
HD 170740 21.46 0.51 14.69+0.10−0.10 2.91 ± 0.14 0.47 ± 0.01 2.92 ± 0.10 0.94 ± 0.01 1,2,4
HD 177989 21.06 0.23 14.95+0.06−0.06 2.85 ± 0.27 0.22 ± 0.01 2.40 ± 0.22 0.93 ± 0.04 2,3,4
HD 179406 21.44 0.39 14.72+0.17−0.15 2.88 ± 0.20 0.31 ± 0.01 3.72 ± 0.23 0.96 ± 0.03 2,3,4
HD 185418 21.39 0.47 15.00+0.12−0.10 2.48 ± 0.13 0.47 ± 0.01 3.64 ± 0.12 0.88 ± 0.01 1,2,4
HD 197512 21.44 0.33 15.06+0.15−0.12 2.43 ± 0.15 0.29 ± 0.01 4.14 ± 0.18 0.97 ± 0.02 1,2,4
HD 199579 21.25 0.38 14.87+0.27−0.07 3.05 ± 0.17 0.33 ± 0.01 2.63 ± 0.17 0.97 ± 0.03 1,2,4
HD 209339 21.24 0.18 15.09+0.04−0.04 3.10 ± 0.10 0.35 ± 0.01 2.33 ± 0.11 0.81 ± 0.01 2,3,4

Notes. Column (1) is the HD name of background early type Galactic stars. Columns (2)–(4) are adopted from references 1, 2, and 4. Columns (5)–(8) are adopted from reference 3. aN(Htot) = N(H i)+N(H2) column densities are measured by Voigt profile fitting. bInitial N(Fe ii) was measured by curve of growth analysis of Fe ii weak/moderate strength transitions in Snow et al. (2002) and Jensen & Snow (2007). Jenkins (2009) corrected the N(Fe ii) by using most modern Fe ii f-values. We adopt the corrected N(Fe ii) in this work. References. (1) Snow et al. 2002; (2) Fitzpatrick & Massa 2007; (3) Jensen & Snow 2007; (4) Jenkins 2009.

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In Figure 9(c), we confirm the anti-correlation between f (H2) and [Fe/H] (Spearman's ρ = −0.81) and interpret it as the simultaneous dissociation of molecular hydrogen with destruction of large dust grain. In addition, we find a tentative correlation between dust-to-gas ratio and [Fe/H] with Spearman's ρ = +0.54 (Figure 9(d)). It is consistent with the grain destruction scenario. Assuming constant density and spherical dust grains, the total cross section of finer grains would be greater than the total cross section of large grains even if some materials of dust grains are evaporated during the destruction processes. We summarize the discussions as a molecule and large grain destruction scenario: (1) molecules (e.g., PAH and H2) and large dust grains form substantially in cool and dense environment; (2) molecules and large grains would be destroyed simultaneously when the environment is heated (e.g., heated by supernova shock waves; irradiated by extreme UV photons); and (3) the destruction of large dust grains releases some depleted elements into the gas phase; the dissociation of H2 molecules decreases the f (H2), while the dissociation of PAH molecules diminishes the strength of 2175 Å absorption bump.

7. FUTURE WORK AND CONCLUSION

In this work, we measure the dust depletion levels for the two 2175 Å absorbers. More observations in other wavelength bands will definitely help us to unveil the astrophysical conditions giving rise to 2175 Å absorption. For the two absorbers at z ∼ 1.4 in this work, the HST/COS13 spectrometer covers the important H i and H2 transitions and can be used to determine the gas metallicity and f (H2). We are planning to propose Keck/HIRES observations to catch the C i and other transitions blueward of the ESI coverage to the atmospheric cutoff. Atomic carbon is an excellent tracer of cold, dense gas because of its low ionization potential (below 1 Ryd). The ratios of C i and C ii transitions will provide us a powerful tool to probe the physical environment of the absorbers.

By using the parameterized extinction curve fitting technique, we are searching for more 2175 Å absorbers in SDSS quasar spectra database. Our preliminary result shows 18 detections of 2175 Å extinction bump associated with dusty strong Mg ii quasar absorbers in SDSS DR3.

In this paper, we report on follow-up moderate resolution spectroscopy of the 2175 Å absorption systems at z∼ 1.4 in lines of sight toward two quasars J0121+0027 and J1459+0024. The column densities of heavy elements are measured by low-ionization absorption lines with AODM. We derived the dust depletion patterns of both absorption systems and found that they closely resemble that of cold diffuse disk clouds in MW. The values, [Fe/Zn] ≈−1.5 and [Si/Zn]<−0.67, are among the highest dust depletion measured for QAL systems. We conclude that heavy dust depletion (i.e., a characteristic of cold dense clouds in MW) is required to produce a pronounced 2175 Å extinction bump.

This work was partially supported by NSF with grant NSF AST-0451407, AST-0451408, and AST-0705139 and a China NSF grant (NSF-10973012). P.J acknowledges support from China Scholarship Council. This research has also been partially supported by the CAS/SAFEA International Partnership Program for Creative Research Teams. J.X.P. is partially supported by an NSF CAREER grant (AST-0548180) and by NSF grant AST-0908910.

The authors recognize and acknowledge the very significant cultural role and reverence that the summit of Mauna Kea has always had within the indigenous Hawaiian community. We are most fortunate to have the opportunity to conduct observations from this mountain.

Funding for the SDSS and SDSS-II has been provided by the Alfred P. Sloan Foundation, the Participating Institutions, the National Science Foundation, the U.S. Department of Energy, the National Aeronautics and Space Administration, the Japanese Monbukagakusho, the Max Planck Society, and the Higher Education Funding Council for England. The SDSS Web site is http://www.sdss.org/.

The SDSS is managed by the Astrophysical Research Consortium for the Participating Institutions. The Participating Institutions are the American Museum of Natural History, Astrophysical Institute Potsdam, University of Basel, University of Cambridge, Case Western Reserve University, University of Chicago, Drexel University, Fermilab, the Institute for Advanced Study, the Japan Participation Group, Johns Hopkins University, the Joint Institute for Nuclear Astrophysics, the Kavli Institute for Particle Astrophysics and Cosmology, the Korean Scientist Group, the Chinese Academy of Sciences (LAMOST), Los Alamos National Laboratory, the Max-Planck-Institute for Astronomy (MPIA), the Max-Planck-Institute for Astrophysics (MPA), New Mexico State University, Ohio State University, University of Pittsburgh, University of Portsmouth, Princeton University, the United States Naval Observatory, and the University of Washington.

Footnotes

  • The data presented herein were obtained at the W. M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and the National Aeronautics and Space Administration. The Observatory was made possible by the generous financial support of the W. M. Keck Foundation.

  • Sloan Digital Sky Survey; http://www.sdss.org/

  • The SDSS spectra in Wang et al. (2004) were extracted from Data Release 1 (DR1; Abazajian et al. 2003), while the SDSS spectra in this work are extracted from DR7 (Abazajian et al. 2009). All the SDSS spectra in this work are corrected for the Galactic reddening by using the dust map of Schlegel et al. (1998) before being analyzed.

  • The linear component also accounts for the variation of the intrinsic quasar spectral slopes.

  • Most of the false positive detections of quasar can be rejected by this criterion: SN_I = 18 for J1459+0024 and SN_I = 8 for J0121+0027.

  • 10 

    There are 2204 quasar spectra being used to create the SDSS quasar composite spectrum in total.

  • 11 

    The possible different underlying nucleosynthetic pattern can induce an error at the level of a few tenths dex (e.g., Lu et al. 1996; Prochaska et al. 2000). This error is likely to decrease in high metallicity absorbers, where less massive stars are more likely to dominate nucleosynthetic procedure.

  • 12 

    X could be Zn, Si, or S.

  • 13 
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10.1088/0004-637X/724/2/1325