Zinc oxide (ZnO) films have been grown on gold (111) by electrodeposition using two different OH− sources, nitrate and peroxide, in order to obtain a comparative study between them. The morphology, structural and optical characterization of the films were investigated depending on the solution used (nitrate and peroxide) and the applied potential. Scanning electron microscopy pictures show different morphologies in each case. X-ray diffraction confirms that the films are pure ZnO oriented along the (0002) direction. ZnO films have been studied by photoluminescence to identify the emission of defects in the visible range. A consistent model that explains the emissions for the different electrodeposited ZnO films is proposed. We have associated the green and yellow emissions to a transition from the donor OH− to the acceptor zinc vacancies (VZn−) and to interstitial oxygen (Oi0), respectively. The orange-red emission is probably due to transitions from the conducting band to Oi− and OZn0 defects and the infrared emission to transition from these Oi−/2− and OZn0/− defects to the valence band.
Skip Nav Destination
Article navigation
15 August 2011
Research Article|
August 31 2011
Synthesis and luminescence properties of electrodeposited ZnO films
C. V. Manzano;
C. V. Manzano
IMM-Instituto de Microelectrónica de Madrid (CNM-CSIC), Isaac Newton 8
, PTM, E-28760 Tres Cantos, Madrid, Spain
Search for other works by this author on:
D. Alegre;
D. Alegre
IMM-Instituto de Microelectrónica de Madrid (CNM-CSIC), Isaac Newton 8
, PTM, E-28760 Tres Cantos, Madrid, Spain
Search for other works by this author on:
O. Caballero-Calero;
O. Caballero-Calero
IMM-Instituto de Microelectrónica de Madrid (CNM-CSIC), Isaac Newton 8
, PTM, E-28760 Tres Cantos, Madrid, Spain
Search for other works by this author on:
B. Alén;
B. Alén
IMM-Instituto de Microelectrónica de Madrid (CNM-CSIC), Isaac Newton 8
, PTM, E-28760 Tres Cantos, Madrid, Spain
Search for other works by this author on:
M. S. Martín-González
M. S. Martín-González
a)
IMM-Instituto de Microelectrónica de Madrid (CNM-CSIC), Isaac Newton 8
, PTM, E-28760 Tres Cantos, Madrid, Spain
Search for other works by this author on:
a)
Author to whom correspondence should be addressed. Electronic mail: marisol@imm.cnm.csic.es.
J. Appl. Phys. 110, 043538 (2011)
Article history
Received:
March 22 2011
Accepted:
July 06 2011
Citation
C. V. Manzano, D. Alegre, O. Caballero-Calero, B. Alén, M. S. Martín-González; Synthesis and luminescence properties of electrodeposited ZnO films. J. Appl. Phys. 15 August 2011; 110 (4): 043538. https://doi.org/10.1063/1.3622627
Download citation file:
Sign in
Don't already have an account? Register
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Sign in via your Institution
Sign in via your InstitutionPay-Per-View Access
$40.00
Citing articles via
A step-by-step guide to perform x-ray photoelectron spectroscopy
Grzegorz Greczynski, Lars Hultman
GaN-based power devices: Physics, reliability, and perspectives
Matteo Meneghini, Carlo De Santi, et al.