Rapid Fluorodesilylation of Aryltrimethylsilanes Using Xenon Difuoride: An Efficient New Route to Aromatic Fluorides

Aileen P. Lothian; Christopher A. Ramsden

doi:10.1055/s-1993-22596

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Synlett 1993; 1993(10): 753-755
DOI: 10.1055/s-1993-22596

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Rapid Fluorodesilylation of Aryltrimethylsilanes Using Xenon Difuoride: An Efficient New Route to Aromatic Fluorides

Aileen P. Lothian^* , Christopher A. Ramsden

^*Department of Chemistry, Keele University, Keele, Staffordshire ST5 5BG, England

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Publication Date:
19 March 2002 (online)

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The reaction of aryltrimethylsilanes (1) with xenon difluoride in C₆F₆ at room temperature results in the rapid and clean formation of arylfluorides (2). Evidence that the reaction proceeds via arylradicals (8) is presented.

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