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Synthesis 2024; 56(09): 1369-1380
DOI: 10.1055/a-2193-4927
DOI: 10.1055/a-2193-4927
short review
Recent Progress in Developing Thioether-Containing Ligands for Catalysis Applications
This work was supported by the Centre National de la Recherche Scientifique (CNRS) and the University of Strasbourg.
Abstract
The ligand that stabilizes the metal center is crucial to its catalytic activity. Historically dominated by phosphorus and nitrogen, sulfur has long been little considered as a hetero element for stabilizing a potentially active metal center. However, this situation is changing and we are seeing more and more examples that incorporate this element. This review provides an overview of recent transition-metal-catalyzed reactions with ligands containing neutral sulfur groups, i.e. thioethers. A selection of examples published since 2013 illustrates the diversity of applications of thioether-containing ligands and shows that sulfur should be more widely used in the development of homogeneous catalysis.
1 Introduction
2 Phosphorus-Thioether Ligands
3 Nitrogen-Thioether Ligands
4 Oxygen-Thioether Ligands
5 NHC-Thioether Ligands
6 Cycloolefin-Thioether Ligands
7 Conclusion
Key words
Homogeneous catalysis - S,N ligands - S,P ligands - S,NHC ligand - S,O ligands - thioether ligandsPublication History
Received: 07 September 2023
Accepted after revision: 17 October 2023
Accepted Manuscript online:
17 October 2023
Article published online:
27 November 2023
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