Volume 66, 1970
From the journal:

Transactions of the Faraday Society

Pulse radiolytic induced transient electrical conductance in liquid solutions. Part 2.—Radiolysis of aqueous solutions of NO –3, NO –2 and Fe(CN) 3–6

G. C. Barker,   P. Fowles  and  B. Stringer  

Abstract

A study has been made of the radiolysis of aqueous solutions of NO–3, NO–2 and Fe (CN)3–6 within the first millisecond after exposure to a submicrosecond pulse of 15 MeV electrons. The overall reaction of the electron adduct of NO–3 with water has a time constant of 9.5 µs at 25°C and it is catalyzed by H+. The reduction product of nitrite, 2OH–, appears to originate from two processes with time constants of 18 and < 2µs respectively. The reduction of ferricyanide is probably complicated by aquocomplex formation. The rate constant for CH2OH + Fe(CN)3–6→ CH2O + H++ Fe(CN)4–6 is 4.2 × 109 l. mol–1 s–1.

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Article information

DOI
https://doi.org/10.1039/TF9706601509
Article type
Paper

Trans. Faraday Soc., 1970,66, 1509-1519

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Pulse radiolytic induced transient electrical conductance in liquid solutions. Part 2.—Radiolysis of aqueous solutions of NO–3, NO–2 and Fe(CN)3–6

G. C. Barker, P. Fowles and B. Stringer, Trans. Faraday Soc., 1970, 66, 1509 DOI: 10.1039/TF9706601509

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