Issue 6, 1986

The geometry at nitrogen in N-phenylsulphonyl-pyrroles and -indoles. The geometry of sulphonamides

Abstract

The structures of 1-phenylsulphonylpyrrole, 1-phenylsulphonylindole, 4,5,6,7-tetrahydro-1-phenylsulphonylindole, and 1,2,3,4-tetrahydro-9-phenylsulphonylcarbazole have been determined by X-ray crystallography. The heterocyclic nitrogen is planar in some and pyramidal in others. A preferred geometry for the PhSO2N unit emerged from the structures; it is compared with available data for sulphonamides.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1986, 787-797

The geometry at nitrogen in N-phenylsulphonyl-pyrroles and -indoles. The geometry of sulphonamides

R. L. Beddoes, L. Dalton, J. A. Joule, O. S. Mills, J. D. Street and C. I. F. Watt, J. Chem. Soc., Perkin Trans. 2, 1986, 787 DOI: 10.1039/P29860000787

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