Issue 0, 1972
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Diterpenes. Part X. Some transformations of phyllocladene and isophyllocladene

K. M. Baker,   Lindsay H. Briggs,   J. G. St. C. Buchanan,   R. C. Cambie,   B. R. Davis,   R. C. Hayward,   G. A. S. Long  and  P. S. Rutledge  

Abstract

The products from, and the effect of solvent on the ring-opening of 15α,16-epoxyphyllocladane (1) and of 16,17-epoxyphyllocladane (17) with boron trifluoride have been examined. The action of other Lewis acids has also been investigated. Treatment of 15α,16-epoxykaurane (21) with boron trifluoride–ether complex results in rearrangement, giving atisiran-15-one (25).

Photo-oxygenation of phyllocladene (6) and isophyllocladene (19) has been studied; a minor product from the latter reaction is 15α,16-epoxyphyllocladan-17-ol (2).

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/P19720000190
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1972, 190-194

Permissions

Request permissions

Diterpenes. Part X. Some transformations of phyllocladene and isophyllocladene

K. M. Baker, L. H. Briggs, J. G. St. C. Buchanan, R. C. Cambie, B. R. Davis, R. C. Hayward, G. A. S. Long and P. S. Rutledge, J. Chem. Soc., Perkin Trans. 1, 1972, 190 DOI: 10.1039/P19720000190

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements