The reaction of n-alkanesulphenyl halides with a number of pyrimidines, in which the pyrimidine 5-position is unsubstituted but which carry at least two strongly electron-releasing substituents gives 5-alkylthiopyrimidines in good yield.
E. A. Gray, R. M. Hulley and B. K. Snell, J. Chem. Soc. C, 1970, 986 DOI: 10.1039/J39700000986
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