A strong-base ion-exchange resin converts 1-O-toluene-p-sulphonylmyoinositol into 1,2-anhydro-(±)-inositol but, unlike sodium hydroxide, does not cause subsequent epoxide migration. Acid hydrolysis of the anhydro-compound gives mainly mucoinositol. The configurations of “bromoscylloquercitol” and “bromoviboquercitol” have been established.
S. J. Angyal, V. Bender and J. H. Curtin, J. Chem. Soc. C, 1966, 798 DOI: 10.1039/J39660000798
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