The solid-state structure of diethylamino(methyl)carbenepentacarbonylchromium is compared with those of other transition-metal carbene complexes. The crystals are triclinic, with a= 11·31 ± 0·02, b= 9·06 ± 0·02, c= 7·46 ± 0·01 Å, α= 71° 5′± 15′, β= 80° 30′± 10′, γ= 68° 59′± 10′. The space-group is P![[1 with combining macron]](https://www.rsc.org/images/entities/char_0031_0304.gif)
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J. A. Connor and O. S. Mills, J. Chem. Soc. A, 1969, 334 DOI: 10.1039/J19690000334
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