Issue 0, 1966
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Preparation and properties of tristrifluoromethylhydrazyl compounds

R. C. Dobbie  and  H. J. Emeléus  

Abstract

N-Chlorobistrifluoromethylamine reacts with cyanogen chloride on irradiation to give bistrifluoromethylaminocarbylamine chloride, (CF3)2N·N:CCl2. Fluorination of the carbylamine chloride with sodium fluoride gives (C3F8N2)2; a structure for the dimer is proposed. Reaction with mercuric fluoride produces a crystalline mercurial, [(CF3)2N·N(CF3)]2Hg. Perfluorohexamethyltetrazine, N-bromotristrifluoromethylhydrazine, tristrifluoromethylhydrazine, and N-nitrosotristrifluoromethylhydrazine have been prepared from the mercurial by reactions with halogen-containing compounds.

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Article information

DOI
https://doi.org/10.1039/J19660000933
Article type
Paper

J. Chem. Soc. A, 1966, 933-935

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Preparation and properties of tristrifluoromethylhydrazyl compounds

R. C. Dobbie and H. J. Emeléus, J. Chem. Soc. A, 1966, 933 DOI: 10.1039/J19660000933

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