Issue 0, 1966
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Heats of formation and bond energies. Part XV. Chlorotrimethylsilane and hexamethyldisilazane

A. E. Beezer  and  C. T. Mortimer  

Abstract

The heats of hydrolysis of chlorotrimethylsilane in water, and of hexamethyldisilazane in an aqueous solution of excess hydrogen chloride, to give hexamethyldisiloxane and an aqueous solution of hydrogen chloride, and also ammonium chloride in the second case, have been measured. These data are used to calculate the values ΔHf°(Me3SiCl, liq.)=–91·9 ± 0·8 kcal./mole and ΔHf°[(Me3Si)2NH, liq.]=–123·8 ± 1·4 kcal./mole. Bond energies in some silicon compounds are derived.

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Article information

DOI
https://doi.org/10.1039/J19660000514
Article type
Paper

J. Chem. Soc. A, 1966, 514-516

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Heats of formation and bond energies. Part XV. Chlorotrimethylsilane and hexamethyldisilazane

A. E. Beezer and C. T. Mortimer, J. Chem. Soc. A, 1966, 514 DOI: 10.1039/J19660000514

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