Issue 0, 1980

Electron spin resonance detection of spin-trapped radicals formed during the glow-discharge electrolysis of aqueous solutions

Abstract

Hydrogen atoms and hydroxyl radicals produced in the glow-discharge electrolysis of aqueous solutions have been identified by e.s.r. spectroscopy using 5,5-dimethylpyrroline-1-oxide (DMPO) as a spin trap. The trap is able to penetrate the primary reaction zone (at the discharge/solution interface) to scavenge for free radicals. No evidence for the presence of hydrated electrons (eaq) was found.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1980,76, 648-653

Electron spin resonance detection of spin-trapped radicals formed during the glow-discharge electrolysis of aqueous solutions

A. T. Bullock, D. L. Gavin and M. D. Ingram, J. Chem. Soc., Faraday Trans. 1, 1980, 76, 648 DOI: 10.1039/F19807600648

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements