Issue 33, 2023

A cis-β-iron(iii) SALPN catalyst for hydrogen atom transfer reductions and olefin cross couplings

Abstract

An inexpensive Fe(III) SALPN catalyst for MHAT reactions such as reductions of α,β-unsaturated carbonyl compounds and olefin cross couplings is reported. The majority of these reactions proceeded in good yields and high stereoselectivities with low catalyst loadings at room temperature.

Graphical abstract: A cis-β-iron(iii) SALPN catalyst for hydrogen atom transfer reductions and olefin cross couplings

Supplementary files

Article information

Article type
Paper
Submitted
06 Jul 2023
Accepted
01 Aug 2023
First published
01 Aug 2023

Org. Biomol. Chem., 2023,21, 6789-6793

A cis-β-iron(III) SALPN catalyst for hydrogen atom transfer reductions and olefin cross couplings

M. Ricca, S. Yao, T. Le, J. M. White, P. S. Donnelly and M. A. Rizzacasa, Org. Biomol. Chem., 2023, 21, 6789 DOI: 10.1039/D3OB01085F

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