Issue 16, 2024
From the journal:

Chemical Communications

Insights into non-covalent interactions in dicopper(ii,ii) complexes bearing a naphthyridine scaffold: anion-dictated electrochemistry†

Jonathan De Tovar, ORCID logo *a   Christian Philouze,a   Aurore Thibon-Pourret ORCID logo a  and  Catherine Belle ORCID logo a  

* Corresponding authors

a Université Grenoble Alpes, CNRS, DCM, UMR 5250, 38000 Grenoble, France
E-mail: Jonathan.De-Tovar@univ-grenoble-alpes.fr

Abstract

A family of bis(μ-hydroxido)dicopper(II,II) complexes bearing a naphthyridine-based scaffold has been synthesized and characterized. Cyclic voltammetry reveals that the nature of the anions present in the complexes plays a pivotal role in their electrochemical properties. X-ray diffraction, spectroscopic and electrochemical analysis data support the formation of intimate ion pairs by non-covalent interactions driving to a ca. 270 mV difference for the potential required to monooxidize the CuIICuII species.

Graphical abstract: Insights into non-covalent interactions in dicopper(ii,ii) complexes bearing a naphthyridine scaffold: anion-dictated electrochemistry

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Article information

DOI
https://doi.org/10.1039/D3CC06264C
Article type
Communication
Submitted
25 Dec 2023
Accepted
26 Jan 2024
First published
30 Jan 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 2228-2231

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Insights into non-covalent interactions in dicopper(II,II) complexes bearing a naphthyridine scaffold: anion-dictated electrochemistry

J. De Tovar, C. Philouze, A. Thibon-Pourret and C. Belle, Chem. Commun., 2024, 60, 2228 DOI: 10.1039/D3CC06264C

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