SCHEDULED MAINTENANCE
Phase-transition engineering induced lattice contraction of the molybdenum carbide surface for highly efficient hydrogen evolution reaction†
Abstract
The electrochemical hydrogen evolution reaction (HER) has been considered as an efficient way of producing hydrogen energy. Molybdenum carbide has received a lot of attention as an important catalyst because of its noble metal-like surface electronic properties. However, the effect of surface reconstruction of molybdenum carbide during phase transition on electrocatalysis has attracted little attention. Herein, different degrees of the lattice contraction effect on the α-MoC surface are discovered during the phase-transition from cubic α-MoC to hexagonal β-Mo2C by CH4/H2 pretreatment. Density functional theory (DFT) calculations reveal that the lattice contraction imposed on the molybdenum carbide surface results in a downshift of the d-band center and then intensively regulates the Mo–H binding energy and ΔGH* value close to thermodynamic neutral, which greatly enhances the HER kinetics. Benefiting from these, the optimized α-MoC-5 h (α-MoC pretreated in a CH4/H2 atmosphere for 5 h) with a lattice contraction degree of 2.86% manifests a much lower overpotential (η10 = 126 mV in 1 M HClO4; η10 = 122 mV in 1 M KOH), which is 2-fold lower than that of untreated α-MoC, and exhibits good stability over 120 hours. This work unravels the underlying lattice contraction effect of α-MoC on the phase-transition process during thermal pretreatment, which deepens the understanding of molybdenum carbide and provides inspiration for the design of other metal carbides.
- This article is part of the themed collection: Journal of Materials Chemistry A HOT Papers
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