Issue 32, 2022

Construction of a ternary MoO2/Ni/C hybrid towards lithium-ion batteries as a high-performance electrode

Abstract

Although the advantages of transition metal oxides (TMOs) include low cost, convenient synthesis and high capacity, the severe volume expansion and modest conductivity restrain their extensive applications. In this work, we introduced carbon sources into MoO2/Ni materials by high temperature annealing, and successfully obtained MoO2/Ni/C composites with a three-dimensional (3D) flower-like structure. In addition, the outermost carbon coating can efficaciously boost the electrical conductivity of the MoO2/Ni/C and buffer its volumetric expansion. As expected, the MoO2/Ni/C sample shows a high lithium storage capacity of 808 mA h g−1 after 200 cycles at 200 mA g−1 when utilized as a lithium-ion battery (LIB) anode. Therefore, it also provides guidance for the construction and optimization of carbon-coated TMO anode materials for LIBs.

Graphical abstract: Construction of a ternary MoO2/Ni/C hybrid towards lithium-ion batteries as a high-performance electrode

Supplementary files

Article information

Article type
Paper
Submitted
01 Mar 2022
Accepted
26 Jun 2022
First published
05 Jul 2022

New J. Chem., 2022,46, 15451-15459

Construction of a ternary MoO2/Ni/C hybrid towards lithium-ion batteries as a high-performance electrode

J. Shen, G. Duan, X. Guo, G. Yang, L. Li and B. Cao, New J. Chem., 2022, 46, 15451 DOI: 10.1039/D2NJ01026G

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