Issue 47, 2022

Efficient improvement of the lithium ionic conductivity for a polymer electrolyte via introducing porous metal–organic frameworks

Abstract

The electrolyte membrane plays a vital role in the practical conduction application of lithium-ion batteries. In this study, a series of PVDF–HFP/MOF-5 composite electrolyte materials were harvested by incorporating MOF-5 into PVDF–HFP, presenting excellent electrochemical characteristics and mechanical properties. Importantly, the performances of the PVDF–HFP/MOF-5 composites depended greatly on the content of MOF-5 introduced and the channels change. The PVDF–HFP/MOF-5-II with a MOF-5 content of 2 wt% revealed optimal ionic conductivity of 1.20 × 10−3 S cm−1 and lithium ion transference number of 0.9 at room temperature, which shows potential application prospects in the field of electrolyte materials.

Graphical abstract: Efficient improvement of the lithium ionic conductivity for a polymer electrolyte via introducing porous metal–organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
14 Mar 2022
Accepted
13 May 2022
First published
14 May 2022

Chem. Commun., 2022,58, 6717-6720

Efficient improvement of the lithium ionic conductivity for a polymer electrolyte via introducing porous metal–organic frameworks

L. Tian, F. Tao, X. Wang, M. Liu, X. Kang and Z. Liu, Chem. Commun., 2022, 58, 6717 DOI: 10.1039/D2CC01458K

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