Issue 38, 2022
From the journal:

Chemical Communications

Aziridinium cation templating 3D lead halide hybrid perovskites†

Hanna R. Petrosova,a   Olesia I. Kucheriv, ORCID logo a   Sergiu Shovab  and  Il'ya A. Gural'skiy ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, Ukraine
E-mail: illia.guralskyi@univ.kiev.ua

b Department of Inorganic Polymers, Petru Poni Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41-A, Iasi 700487, Romania

Abstract

This study describes the synthesis of the first aziridinium-based compounds, namely hybrid perovskites (AzrH)PbHal3 (where AzrH = aziridinium, Hal = Cl, Br or I). This highly reactive species was stabilized in 3D lead halide frameworks and was found to be a small enough organic cation to promote the formation of semiconducting organo-inorganic materials.

Graphical abstract: Aziridinium cation templating 3D lead halide hybrid perovskites

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Article information

DOI
https://doi.org/10.1039/D2CC01364A
Article type
Communication
Submitted
07 Mar 2022
Accepted
29 Mar 2022
First published
21 Apr 2022

Chem. Commun., 2022,58, 5745-5748

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Aziridinium cation templating 3D lead halide hybrid perovskites

H. R. Petrosova, O. I. Kucheriv, S. Shova and I. A. Gural'skiy, Chem. Commun., 2022, 58, 5745 DOI: 10.1039/D2CC01364A

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