Synthesis and photophysical properties of novel oxadiazole substituted BODIPY fluorophores

Maria D. Matveeva; Dmitry I. Zhilyaev; Almira R. Miftyakhova; Pavel Chulkin; Patryk Janasik; Leonid G. Voskressensky; Giovanni Talarico; Ilya V. Efimov

doi:10.1039/D1NJ05317E

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Synthesis and photophysical properties of novel oxadiazole substituted BODIPY fluorophores†

Maria D. Matveeva,

*^a Dmitry I. Zhilyaev,^b Almira R. Miftyakhova,^b Pavel Chulkin,^c Patryk Janasik,^c Leonid G. Voskressensky,

^b Giovanni Talarico

*^d and Ilya V. Efimov

Author affiliations

* Corresponding authors

^a A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky pr. 29, Moscow, Russian Federation
E-mail: m.d.matveeva@gmail.com

^b Research Center, Molecular Design and Synthesis of Innovative Compounds for Medicine, RUDN University, Miklukho-Maklaya st, 6, Moscow, Russia

^c Department of Physical Chemistry and Technology of Polymers, Faculty of Chemistry, Silesian University of Technology, Strzody 9, Gliwice 44-100, Poland

^d Dipartimento di Scienze Chimiche, Università di Napoli Federico II, Via Cintia, Napoli, Italy
E-mail: talarico@unina.it

Abstract

Using 3-phenyl-5-(5-phenyl-1H-pyrrol-3-yl)-1,2,4-oxadiazole, BODIPYs with the oxadiazole groups at the 1,7-positions were prepared and their photophysical properties were characterized. The method employs 2,4-diphenyl substituted pyrrole and various aromatic aldehydes under solvent-free conditions. Due to the attachment of the oxadiazole groups at the 1,7-positions, the BODIPYs show long-wavelength absorption and emission in the near-infrared region.

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DOI: https://doi.org/10.1039/D1NJ05317E
Article type: Paper
Submitted: 08 Nov 2021
Accepted: 07 Feb 2022
First published: 09 Feb 2022

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New J. Chem., 2022,46, 5725-5729

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Synthesis and photophysical properties of novel oxadiazole substituted BODIPY fluorophores

M. D. Matveeva, D. I. Zhilyaev, A. R. Miftyakhova, P. Chulkin, P. Janasik, L. G. Voskressensky, G. Talarico and I. V. Efimov, New J. Chem., 2022, 46, 5725 DOI: 10.1039/D1NJ05317E

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New Journal of Chemistry

Synthesis and photophysical properties of novel oxadiazole substituted BODIPY fluorophores†

Abstract

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Synthesis and photophysical properties of novel oxadiazole substituted BODIPY fluorophores

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