A site-specific deprotonation followed by alkylations and acylations of sugar hemiacetals to the corresponding alkyl glycosides and acylated sugars in aqueous solutions is disclosed herein. Pyridoneimine as a new base is developed to mediate the deprotonation of readily available sugar hemiacetals and further reactions with alkylation and acylation agents.
K. Dey and N. Jayaraman, Chem. Commun., 2022, 58, 2224 DOI: 10.1039/D1CC07056H
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