Bis-acenaphthoquinone diimides with high electron deficiency and good coplanar conformation

Xin Yang; Yongkun Yan; Weixuan Zeng; Ying Song; Wenhao Li; Lingli Zhao; Yan Zhao; Huajie Chen; Yunqi Liu

doi:10.1039/D1CC02693C

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Bis-acenaphthoquinone diimides with high electron deficiency and good coplanar conformation†

Xin Yang,‡^a Yongkun Yan,‡^b Weixuan Zeng,

^c Ying Song,^a Wenhao Li,^b Lingli Zhao,^a Yan Zhao,*^b Huajie Chen

*^a and Yunqi Liu^b

Author affiliations

* Corresponding authors

^a Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China
E-mail: chenhjoe@163.com

^b Laboratory of Molecular Materials and Devices, Department of Materials Science, Fudan University, Shanghai 200438, China
E-mail: zhaoy@fudan.edu.cn

^c Department of Chemistry, University of Cambridge, Cambridge, UK

Abstract

A series of novel bis-acenaphthoquinone diimides featuring a highly electron-deficient bis-acenaphthoquinone core are facilely synthesized via Knoevenagel condensation reaction. The diimides show high electron deficiency and good coplanar conformation, together with one of them having a maximum electron mobility up to 0.038 cm² V⁻¹ s⁻¹.

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DOI: https://doi.org/10.1039/D1CC02693C
Article type: Communication
Submitted: 22 May 2021
Accepted: 06 Jul 2021
First published: 07 Jul 2021

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Chem. Commun., 2021,57, 7822-7825

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Bis-acenaphthoquinone diimides with high electron deficiency and good coplanar conformation

X. Yang, Y. Yan, W. Zeng, Y. Song, W. Li, L. Zhao, Y. Zhao, H. Chen and Y. Liu, Chem. Commun., 2021, 57, 7822 DOI: 10.1039/D1CC02693C

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Chemical Communications

Bis-acenaphthoquinone diimides with high electron deficiency and good coplanar conformation†

Abstract

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Bis-acenaphthoquinone diimides with high electron deficiency and good coplanar conformation

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